In 1999, the DEECA/INETI and the UBiA/FCT/UNL started a researching project on the partition of heavy metals during the combustion of stabilised sewage sludge (Biogran®), in a fluidised-bed reactor, and on the quality of the bottom ashes and fly ashes produced. This project was entitled Bimetal and was funded by the Portuguese Foundation for Science and Technology. In this paper only the results on the combustion of Biogran® are reported. The combustion process was performed in two different trials, in which different amounts of sewage sludge and time of combustion were applied. Several ash samples were collected from the bed (bottom ashes) and from two cyclones (first cyclone and second cyclone ashes). Sewage sludge, bed material (sand) and ash samples were submitted to the leaching process defined in the European leaching standard EN 12457-2. The eluates were characterized for a set of inorganic chemical species. The ecotoxicological levels of the eluates were determined for two biological indicators (Vibrio fischeri and Daphnia magna). The results were compared with the limit values of the CEMWE French Regulation. The samples were also ranked according to an index based on the chemical characterization of the eluates. It was observed an increase of the concentration of metals along the combustion system. The ashes trapped in the second cyclone, for both combustion trials, showed the highest concentration of metals in the eluates. Chemically, the ashes of the second cyclone were the most different ones. In the ecotoxicological point of view, the ecotoxicity levels of the eluates of the ashes, for both combustion cycles, did not follow the same pattern as observed for the chemical characterization. The ashes of the first cyclone showed the highest ecotoxicity levels for V. fischeri and D. magna. This difference on chemical and ecotoxicological results proves the need for performing both chemical and ecotoxicological characterizations of the sub-products of such type of thermal processes.

Polymeric mortars or concrete are special building materials which can be used to repair or strengthen localized areas of structural elements. Following research on the behaviour of retrofitting reinforced concrete circular columns with FRP composite materials and bearing in mind the high strength of polymer concretes, it was decided to develop a solution to seismic retrofit of reinforced concrete columns with polymer concrete. The mechanical characteristics of different polymer concretes and especially their performance when subjected to cyclic axial compression, several bending tests, and monotonic and cyclic axial compression tests were studied, namely the compressive strength, the tensile strength on bending and the Young's modulus. Columns were also tested under axial compression and cyclic horizontal loads. The results of these tests are shown and interpreted. It is concluded that the improved behaviour in monotonic compression of polymer concrete is essentially associated with better strength characteristics of resin, whereas its superior behaviour under cyclic loading is linked to a smoother aggregate grading curve.

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All European countries are building structures to support collection and recovery of electric and electronic waste (WEEE). In this work, the study of a Portuguese recovery network is presented. A MILP model is developed in order to determine the best WEEE network structure as well as the associated optimal plan. Several different analyses are performed.

We give a survey on generalized Krein algebras \(K_{p,q}^{\alpha,\beta}\) and their applications to Toeplitz determinants. Our methods originated in a paper by Mark Krein of 1966, where he showed that \(K_{2,2}^{1/2,1/2}\) is a Banach algebra. Subsequently, Widom proved the strong Szeg\H{o} limit theorem for block Toeplitz determinants with symbols in \((K_{2,2}^{1/2,1/2})_{N\times N}\) and later two of the authors studied symbols in the generalized Krein algebras \((K_{p,q}^{\alpha,\beta})_{N\times N}\), where \(\lambda:=1/p+1/q=\alpha+\beta\) and \(\lambda=1\). We here extend these results to \(0<\lambda<1\). The entire paper is based on fundamental work by Mark Krein, ranging from operator ideals through Toeplitz operators up to Wiener-Hopf factorization.

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Given graphs G and H, an H-decomposition of G is a partition of the edge set of G such that each part is either a single edge or forms a graph isomorphic to H. Let φH(n) be the smallest number φ such that every graph G of order n admits an H-decomposition with at most φ parts. In the paper it is proved that φH(n)=tr−1(n)+o(n2) for every graph H of chromatic number r≥3, where tr(n) is the maximum size of an r-partite graph of order n. Moreover, when H is bipartite, the authors determine φH(n) with a constant additive error.

In this work the design of a reverse distribution network is studied. Most of the proposed models on the subject are case based and, for that reason, they lack generality. In this paper we try to overcome this limitation and a generalized model is proposed. It contemplates the design of a generic reverse logistics network where capacity limits, multi-product management and uncertainty on product demands and returns are considered. A mixed integer formulation is developed which is solved using standard B&B techniques. The model is applied to an illustrative case.

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In the presentwork we have studied the properties of zinc oxide (ZnO) thin films grown by laser ablation of ZnO targets under different substrate temperature and background oxygen conditions. The ZnO layers were deposited with a Pulsed Laser Deposition (PLD) system on pre-nitrided (0001) sapphire (Al2O3), using the base line of a Nd:YAG laser at 1064 nm. The films were characterized by different structural and optical methods, including X-ray diffraction (XRD), scanning electron microscopy (SEM), optical transmission spectroscopy, and steady-state photoluminescence (PL). XRD analysis with rocking curves and $þeta$–2$þeta$ scans indicates preferential growth along the c-axis direction with a full width at half maximum (FWHM) smaller than 1.5◦. Low-temperature photoluminescence (PL) showed strong excitonic emission near 3.36 eV between 9 and 65 K