The degradation mechanisms of bonded joints between CFRP laminates and steel substrates under severe environmental conditions require more durability data and studies to increase the database and better understand their causes. Studies on bond properties of double-strap CFRP-to-steel bonded joints with two different composite materials as well as adhesive coupons subjected to freeze-thaw cycles for 10,000 h were conducted to reduce that gap. In addition, the equivalent to the number of thermal cycles and their slips induced in the CFRP laminates was replicated by an equivalent (mechanical) loading-unloading history condition imposed by a static tensile machine. The mechanical properties of the adhesive coupons and the strength capacity of the bonded joints were only slightly changed by the artificial aging. It was confirmed that the interfacial bond strength between CFRP and adhesive is critically related to the maximum shear stress and failure mode. The interfacial bond strength between adhesive and steel degraded with the aging. However, the equivalent thermal cyclic bond stress caused no detectable damage on the bond because only the interfacial elastic regime was actually mobilized, which confirmed that pure thermal cycles aging, per se, at the level imposed, have a low impact on the degradation of CFRP-to-steel bonded joints. © 2019 Elsevier Ltd

We report on measurements of the Kβ diagram, valence-to-core (VtC), and hypersatellite X-ray spectra induced in metallic Cr by photon single and double K-shell ionization. The experiment was carried out at the Stanford Synchrotron Radiation Lightsource using the seven-crystal Johann-type hard X-ray spectrometer of the beamline 6-2. For the Kβ diagram and VtC transitions, the present study confirms the line shape features observed in previous works, whereas the K h β hypersatellite transition was found to exhibit a complex spectral line shape and a characteristic low-energy shoulder. The energy shift of the hypersatellite relative to the parent diagram line was deduced from the measurements and compared with the result of extensive multiconfiguration Dirac–Fock (MCDF) calculations. A very good agreement between experiment and theory was found. The MCDF calculations were also used to compute the theoretical line shape of the hypersatellite. A satisfactory agreement was obtained between the overall shapes of the experimental and theoretical spectra, but deviations were observed on the low- and high-energy flanks of the hypersatellite line. The discrepancies were explained by chemical effects, which were not considered in the MCDF calculations performed for isolated atoms.

The estimation of the long-term durability of adhesively bonded interfaces between Fiber Reinforced Polymers (FRP) and concrete substrates is crucial because degradation potentiates FRP premature debonding. One of the main reasons for mistrusting the use of FRP composites is the premature debonding phenomenon, which, associated to degradation, has been preventing their widespread use. In this research work, an analytical model is proposed that introduces ageing to estimate the effects of degradation of Glass (G) FRP externally bonded to concrete. Cycles were used to experimentally accelerate ageing of beam specimens, namely, (i) salt fog cycles; (ii) wet-dry cycles with salted water; (iii) temperature cycles between −10 °C and +30 °C; and (iv) temperature cycles between +7.5 °C and +47.5 °C. Based on the experimental results obtained and a corresponding bond-slip curve, the analytical model predicts the complete debonding process between FRP composites and a substrate. Consequently, the temporal evolution of the degradation of the bonded interfaces can be calculated and compared with the initial situation prior to exposure. The effects of the environmental conditions are reported and compared. © 2018 Elsevier Ltd

This chapter provides an overview of the alpha paleobiodiversity of Angola based on the available fossil record that is limited to the sedimentary rocks, ranging in age from Precambrian to the present. The geological period with the highest paleobiodiversity in the Angolan fossil record is the Cretaceous, with more than 80{%} of the total known fossil taxa, especially marine molluscs, including ammonites as a majority among them. The vertebrates represent about 15{%} of the known fauna and about one tenth of them are species firstly described based on specimens from Angola.

Despite extensive research regarding metal cutting simulation, the current industrial practice very often relies on empirical data when it comes to tool design. In order accurately simulate the cutting process it is not only important to have robust numerical models that closely portray the phenomenon, but also to properly characterize the material taking into account the cutting conditions. The goal of this investigation focuses on the mechanical characterization of the cast aluminum alloy AlSi9Cu3 by conducting both compression and fracture tests. Due to its very good castability, machinability, and attractive mechanical properties, this alloy is widely used in casting industry for the manufacture of automotive components, among others. Besides the experimental characterization, a numerical methodology is proposed for the modeling of the cast alloy, making use of the Johnson–Cook constitutive material model, in Abaqus/CAE. The material model is calibrated based on compression tests at multiple conditions (quasi-static, incremental dynamic and high temperatures). The identified model is then validated by simulation of the ductile fracture tests of notched specimens. The obtained numerical results were consistent with the experimentally obtained, contributing to the validity of the presented characterization technique.

Deterioration of adhesively bonded CFRP/steel systems in salt fog environment, i.e., deicing salts and ocean environments, has to be taken into account in the design of steel strengthened structures. In the present work, monotonic and quasi-static cyclic loading were applied to CFRP-to-steel double strap joints for two kinds of CFRP laminates after being aged for a period of 5000 h to evaluate the bond behavior. The bonded joints exposed to salt fog had a different failure mode than that observed in the control specimens (0 h of exposure). The severe reduction of the maximum bond stress resulted from damage initiation that occurred in the corrosion region of the steel substrate, associated with final partial rupture on the corroded steel substrate around the edge of the bonded area: it was also correlated with reduced load carrying capacity. Results of pseudo-cyclic tests showed that the relationship between a local damage parameter (D) and normalized local dissipated energy (W d /G f ) and the normalized slip increment (ΔS/ΔS ult ) exhibited almost the same trend in the un-aged and aged bonded joints. The normalized slip increment can be seen as a direct indicator for the local and global damage for the un-aged and aged bonded joints. However, monotonic and quasi-static cyclic tests results revealed that the stress concentration due to local corrosion of steel substrate could lead to brittle rupture or accelerated cumulative damage once the aged bonded interface had become weaker. The bonded joints have exhibited also a smaller relative deformation capacity between CFRP and steel. © 2019 Elsevier Ltd

Failure of structural steel members strengthened with Carbon Fibre Reinforced Polymers (CFRP) may occur at the joints CFRP-steel and this study examines variables that alter or explain the corresponding reduction of load capacity for a specific CFRP laminate, adhesive and steel. Factors and parameters likely to be influential like surface treatment prior to bonding, the bonded length, the glass transition temperature (Tg) of the adhesive, the exposure to aggressive environment, the temperature at service and different types of loading were examined. The experimental program selected double strap CFRP-steel bonded joints under shear for the analysis. The steel surfaces to be bonded were subjected to sand blasting (6.3 bar) or abrasive grinding (6.9 bar) corresponding to thorough blast cleaning Sa2; surfaces rusted after exposure to salt fog at 35 °C were also considered. Differences detected in responses of specimens treated by sand or steel spheres blasting were relatively minor. Tests made at increasing ambient temperatures confirmed that service temperature near and above adhesive Tg caused rapid deterioration of ultimate capacity and change of failure modes. Salt fog cycles (SF) originated the most significant losses of joint capacity. Application of cyclic static loading above the critical loading threshold obtained for unaged joints did not reduce the capacity of joints previously aged by freeze-thaw. The same cyclic loading after salt fog cycles, reduced bond capacity and increase the ultimate slip, suggesting larger effective length. Despite the losses of capacity, microscopic changes of structural nature could not be identified. © 2019 Elsevier Ltd

We combined different experimental techniques with a theoretical approach to determine a consistent set of diagram lines energies and binding energies. We propose an original approach consisting in determining the mass attenuation coefficients in an energy range covering the L-, M- and N- absorption edges, including a detailed evaluation of the associated uncertainties, to derive precisely the binding energies. We investigated the Lα, Lβ and M spectra of Gd with an independantly calibrated high-resolution anti-parallel double-crystal x-ray spectrometer. All the lines were identified and found in excellent agreement with the binding energies previously derived. Morever, we identified for the first time M5−O2, M4−O2,3 and M4−N2,3 diagram lines.

The durability of adhesively bonded fiber-reinforced polymers (FRP) and concrete substrates has been the subject of recent studies. The degradation of bonded interfaces conjugated with other factors that affect the interface strength may compromise the potentialities of using FRP in externally bonded reinforced (EBR) concrete structures. However, the estimation of the effects of degradation on these bonded interfaces and the analytical methodologies to quantify them are not fully understood. The present work focuses on a local bond-slip model characterized by two parameters for which the values are obtained experimentally. Then, the determination of the local bond-slip relationship of a glass (G) FRP-to-concrete interface can be estimated. The assessment of the degradation of the bonded interface when subjected to cycles of (1) salt fog; (2) wet-dry environments with salt water; (3) temperatures between −10°C and +30°C; and (4) temperatures between +7.5°C and +47.5°C is presented. The results obtained using the proposed bond-slip model led to the conclusion that after 10,000 h of exposure to temperature cycles between −10°C and +30°C, there was a small change in the GFRP-to-concrete interface performance, whereas the effects on the bonded interface for the specimens subjected to temperature cycles between +7.5°C and +47.5°C were far more most severe.

The durability of adhesively bonded fiber-reinforced polymers (FRP) and concrete substrates has been the subject of recent studies. The degradation of bonded interfaces conjugated with other factors that affect the interface strength may compromise the potentialities of using FRP in externally bonded reinforced (EBR) concrete structures. However, the estimation of the effects of degradation on these bonded interfaces and the analytical methodologies to quantify them are not fully understood. The present work focuses on a local bond-slip model characterized by two parameters for which the values are obtained experimentally. Then, the determination of the local bond-slip relationship of a glass (G) FRP-to-concrete interface can be estimated. The assessment of the degradation of the bonded interface when subjected to cycles of (1) salt fog; (2) wet-dry environments with salt water; (3) temperatures between -10°C and +30°C; and (4) temperatures between +7.5°C and +47.5°C is presented. The results obtained using the proposed bond-slip model led to the conclusion that after 10,000 h of exposure to temperature cycles between -10°C and +30°C, there was a small change in the GFRP-to-concrete interface performance, whereas the effects on the bonded interface for the specimens subjected to temperature cycles between +7.5°C and +47.5°C were far more most severe. © 2019 American Society of Civil Engineers.