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The simultaneous separation and quantification of two casein peptides (IPP, VPP) presenting potent inhibitory activity of angiotensin-converting-enzyme (ACE) and casein in fermented milks was developed. Gradient elution was carried out at a flow-rate of 1 mL/min, using a mixture of two solvents. Solvent A was 0.1% TFA in water and solvent B was acetonitrile-water-trifluoracetic acid 95:5:0.1. The effluent was monitored by UV detector at 214 nm. Calibration curves were constructed in the interval of 0.01-1.0 mg/mL for VPP, 0.005-1.0 mg/mL for IPP, and 0.05-3.0 mg/mL for casein. R 2 invariably exceeded 0.999. The detection limits were 0.004 for VPP, 0.002 mg/mL for IPP, and 0.02 mg/mL for casein. Repeatability of the method was evaluated by six consecutive injections of two standard solutions containing VPP, IPP, and casein. The RSD values for concentration were all below 5.08%. Recovery studies were carried out to determine the accuracy of the method. Recoveries ranged between 88 and 98.2%. The methodology was applied, not only, for the monitorization of VPP, IPP, and casein in commercial fermented milks labeled as presenting anti hypertensive properties, but also, in milk with different degrees of fermentation by L Helveticus, and in other commercial functional fermented milks, such as, those presenting cholesterol lowering properties.

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Nanostructured silicon thin films were produced in a single PECVD (Plasma Enhanced Chemical Vapour Deposition) reactor using an excitation frequency of 27.12 MHz. The process parameters were selected to allow the films' production to be performed at the transition region (from amorphous to microcrystalline), aiming their use in solar cells. The real and imaginary parts of pseudo-dielectric function of these nanostructured films show a shift to higher energies and the order factor reveals an improvement on the short atomic range order of the films produced. The solar cells with a structure of ZGO/p-a-SiC:H/buffer1/buffer2/i-(nc/a-Si:H)/n-a-Si:H/Ag/Al were deposited with nanostructured intrinsic layer, showing a good performances, with current densities of about 14.48 mA/cm2, open circuit voltage of 0.94 V, and fill factor of 0.67, which lead to efficiencies of 9.12%. The solar cell degradation study performed under AM1.5 spectrum conditions up to 100 hours revealed a decrease on the solar cell efficiency of about 8.11%, mainly related to the decreasing of current density. Despite that, the open circuit voltage increases slightly after the degradation.

In this paper, a poly-phase disc motor innovative feeding and control strategy, based on a variable poles approach, and its application to a HTS disc motor, are presented. The stator windings may be electronically commutated to implement a 2, 4, 6 or 8 poles winding, thus changing the motor's torque?speed characteristics. The motor may be a conventional induction motor with a conductive disc rotor, or a new HTS disc motor, with conventional copper windings at its two iron semi-stators, and a HTS disc as a rotor. The conventional induction motor's operation principle is related with the induced electromotive forces in the conductive rotor. Its behaviour, characteristics (namely their torque?speed characteristics for different number of pole pairs) and modelling through Steinmetz and others theories are well known. The operation principle of the motor with HTS rotor, however, is rather different and is related with vortices' dynamics and pinning characteristics; this is a much more complex process than induction, and its modelling is quite complicated. In this paper, the operation was simulated through finite-elements commercial software, whereas superconductivity was simulated by the E-J power law. The Electromechanical performances of both motors where computed and are presented and compared. Considerations about the systems overall efficiency, including cryogenics, are also discussed.

In this paper, a poly-phase disc motor innovative feeding and control strategy, based on a variable poles approach, and its application to a HTS disc motor, are presented. The stator windings may be electronically commutated to implement a 2, 4, 6 or 8 poles winding, thus changing the motor's torque?speed characteristics. The motor may be a conventional induction motor with a conductive disc rotor, or a new HTS disc motor, with conventional copper windings at its two iron semi-stators, and a HTS disc as a rotor. The conventional induction motor's operation principle is related with the induced electromotive forces in the conductive rotor. Its behaviour, characteristics (namely their torque?speed characteristics for different number of pole pairs) and modelling through Steinmetz and others theories are well known. The operation principle of the motor with HTS rotor, however, is rather different and is related with vortices' dynamics and pinning characteristics; this is a much more complex process than induction, and its modelling is quite complicated. In this paper, the operation was simulated through finite-elements commercial software, whereas superconductivity was simulated by the E-J power law. The Electromechanical performances of both motors where computed and are presented and compared. Considerations about the systems overall efficiency, including cryogenics, are also discussed.

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Cork is a natural cellular and electrically insulating material which may have the capacity to store electric charges on or in its cell walls. Since natural cork has many voids, it is difficult to obtain uniform samples with the required dimensions. Therefore, a more uniform material, namely commercial cork agglomerate, usually used for floor and wall coverings, is employed in the present study. Since we know from our previous work that the electrical properties of cork are drastically affected by absorbed and adsorbed water, samples were protected by means of different polymer coatings (applied by spin-coating or soaking). Corona charging and isothermal charging and discharging currents were used to study the electrical trapping and detrapping capabilities of the samples. A comparison of the results leads to the conclusion that the most promising method for storing electric charges in this cellular material consists of drying and coating or soaking with a hydrophobic, electrically insulating polymer such as polytetraflouroethylene (Teflon (R)).

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This study describes the characterisation of whey protein hydrolysates obtained from tryptic hydrolysis to assess their application as ingredients with angiotensin-converting-enzyme (ACE) inhibitory action. The levels of a-lactalbumin (alpha-la) and P-lactoglobulin (beta-lg) remaining after hydrolysis were quantified. Peptides were separated by RP-HPLC, and Ala-Leu-Pro-Met-His-Ile-Arg (ALPMHIR), the most potent beta-lg-derived ACE-inhibitory peptide was monitored. A correlation curve was established for the production of this peptide as a function of hydrolysis time. Heat-induced gelation of hydrolysates was studied by small-deformation rheology. The gelation times and the strength of the final gels were highly dependent on the degree of hydrolysis. Smaller peptides liberated by hydrolysis contributed to the inability of whey protein hydrolysates to gel. (c) 2006 Elsevier Ltd. All rights reserved.

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This paper presents the design of a test rig for an all HTS linear synchronous motor. Although this motor showed to have several unattractive characteristics, its design raised a number of problems which must be considered in future HTS machines design. HTS electromagnetic properties led to the development of new paradigms in electrical machines and power systems, as e. g. in some cases iron removal and consequent assembly of lighter devices. This is due to superconductor's ability to carry high currents with minimum losses and consequent generation in the surrounding air of flux densities much higher than the allowed by ferromagnetic saturation. However, severe restrictions in HTS power devices design that goes further beyond cryogenic considerations must be accounted in. This is usually the case when BSCCO tapes are used as conductors. Its bending limitations and the presence of flux components perpendicular to tape surface, due to the absence of iron, have to be considered for it may turn some possible applications not so attractive or even practically unfeasible. An all HTS linear synchronous motor built by BSCCO tapes as armature conductors and two trapped-flux YBCO bulks in the mover was constructed and thrust force measurements are starting to be performed. Although the device presents severe restrictions due to the exposed and other reasons, it allowed systematising its design. A pulsed-field magnetiser to generate opposite fluxes for both YBCO bulks is also detailed. Thrust force numerical predictions were already derived and presented.

This paper presents the design of a test rig for an all HTS linear synchronous motor. Although this motor showed to have several unattractive characteristics, its design raised a number of problems which must be considered in future HTS machines design. HTS electromagnetic properties led to the development of new paradigms in electrical machines and power systems, as e. g. in some cases iron removal and consequent assembly of lighter devices. This is due to superconductor's ability to carry high currents with minimum losses and consequent generation in the surrounding air of flux densities much higher than the allowed by ferromagnetic saturation. However, severe restrictions in HTS power devices design that goes further beyond cryogenic considerations must be accounted in. This is usually the case when BSCCO tapes are used as conductors. Its bending limitations and the presence of flux components perpendicular to tape surface, due to the absence of iron, have to be considered for it may turn some possible applications not so attractive or even practically unfeasible. An all HTS linear synchronous motor built by BSCCO tapes as armature conductors and two trapped-flux YBCO bulks in the mover was constructed and thrust force measurements are starting to be performed. Although the device presents severe restrictions due to the exposed and other reasons, it allowed systematising its design. A pulsed-field magnetiser to generate opposite fluxes for both YBCO bulks is also detailed. Thrust force numerical predictions were already derived and presented.

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