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The Late Triassic (Norian–early Rhaetian) Fleming Fjord Formation of central East Greenland preserves a diverse fossil fauna, including both body and trace fossils. Trackways of large quadrupedal archosaurs, although already reported in 1994 and mentioned in subsequent publications, are here described and figured in detail for the first time, based on photogrammetric data collected during fieldwork in 2012. Two trackways can be referred to Eosauropus, while a third, bipedal trackway may be referred to Evazoum, both of which have been considered to represent sauropodomorph dinosaur tracks. Both the Evazoum and the Eosauropus trackways are distinctly larger than other trackways referred to the respective ichnogenera. The trackmaker of the best preserved Eosauropus trackway is constrained using a synapomorphy-based approach. The quadrupedal posture, the entaxonic pes structure, and five weight-bearing digits indicate a derived sauropodiform trackmaker. Other features exhibited by the tracks, including the semi-digitigrade pes and the laterally deflected unguals, are commonly considered synapomorphies of more exclusive clades within Sauropoda. The present trackway documents an early acquisition of a eusauropod-like pes anatomy while retaining a well-developed claw on pedal digit IV, which is reduced in eusauropods. Although unequivocal evidence for sauropod dinosaurs is no older than the Early Jurassic, the present trackway provides evidence for a possible Triassic origin of the group.

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Bone grafting and surgical interventions related with orthopaedic disorders consist in a big business, generating large revenues worldwide every year. There is a need to replace the biomaterials that currently still dominate this market, i.e., autografts and allografts, due to their disadvantages, such as limited availability, need for additional surgeries and diseases transmission possibilities. The most promising replacement materials are biomaterials with bioactive properties, such as the calcium phosphate-based bioceramics group. The bioactivity of these materials, i.e., the rate at which they promote the growth and directly bond with the new host biological bone, can be enhanced through their electrical polarization.In the present work, the electrical polarization features of pure hydroxyapatite (Hap), pure β-tricalcium phosphate (β-TCP) and biphasic hydroxyapatite/β-tricalcium phosphate composites (HTCP) were analyzed by measuring thermally stimulated depolarization currents (TSDC). The samples were thermoelectrically polarized at 500. °C under a DC electric field with a magnitude of 5. kV/cm. The biphasic samples were also polarized under electric fields with different magnitudes: 2, 3, 4 and 5. kV/cm. Additionally, the depolarization processes detected in the TSDC measurements were correlated with dielectric relaxation processes observed in impedance spectroscopy (IS) measurements.The results indicate that the β-TCP crystalline phase has a considerable higher ability to store electrical charge compared with the Hap phase. This indicates that it has a suitable composition and structure for ionic conduction and establishment of a large electric charge density, providing great potential for orthopaedic applications.

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Despite increasing calls for evidence-based policies, knowledge about the practical use of evidences remains limited. This paper studies the process of construction of evidences in decisions of innovation policy to understand how evidences were used. It analysis the use of indicators and other evidences through interviews conducted to inquire about the two decisions: an electric mobility policy and a nanotechnology laboratory. Results show indicators and other evidences were brought to decision processes according to their availability and capacity to support the different interests of the actors and
the stakeholders. Their role was influenced by the particular situation of the decision makers. More importantly, the use of persuasive analytical evidences appears to be related with the adversity of the policy context. In addition, research suggests that indicators are one tool among others to foster innovation decisions. In fact, the relatively minor instrumental role of indicators suggests that indicators are mostly a complementary instrument of decision. When used relevantly, indicators can offer support to a decision. But there are other significant influences that need to be taken into account to understand the specific role indicators and other evidences play, such as the social relations of the decision makers and their emotional-intuitive decisions.

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This paper presents a comparative evaluation of efficiencies of different accelerated ageing tests (freezethaw, thermal shock, salt crystallization, dissolution and wetting-drying) and fuzzy inference system in predicting weathering degrees of some monument stones from three historical sites (Anahita Temple, Anobanini reliefs and Eshkaft-e Salman reliefs, Iran). The combined effects of natural weathering processes (heating and cooling, wetting and drying, and freezing and thawing) and climatic information were used for assessing the natural weathering degrees. Finally, the natural weathering degrees were multiplied by time effect coefficients to obtain more realistic natural weathering degrees of the monuments. The predicted natural weathering degrees for Anahita Temple, Anobanini reliefs and Eshkaft-e Salman reliefs are 56%, 61%, and 47%, respectively. These predicted values reasonably support the weathering degrees defined by progressive decay indices (calculated equal to 2.77, 3.42 and 2.66 for Anahita Temple, Anobanini reliefs and Eshkaft-e Salman reliefs, respectively), which means the fuzzy model potentially could accurately predict the weathering of stones.

The electron transfer pathways for the enzymes involved in the four sequential steps of the denitrification pathway are reviewed. In addition, brief information on the electron transfer events is also provided on two enzymes that participate in the dissimilatory nitrate reduction to ammonia. The two main aspects discussed are the intra- and inter-molecular electron transfer pathways and the molecular recognition processes involving the redox partners. When available, information on the residues that are involved in these pathways is given, and their role in electron transfer and/or the formation of the transient electron transfer complexes is discussed. © The Royal Society of Chemistry 2017.

This book is devoted to denitrification, an anaerobic process that is used by a wide range of bacteria for energy generation. The overall process involves nitrate, which is present in soil or water, being reduced to gaseous dinitrogen. This initial chapter aims to place denitrification in the larger context of the nitrogen biogeochemical cycle (a bird's eye view). Detailed topics are developed through the many following contributions. Denitrification is a landscape for probing the structures, functions and mechanisms of action of a wide range of highly specialised metalloenzymes. These carry out, sequentially, four oxo-transfer reactions: NO3 - → NO2 - → NO → N2O → N2. The environmental implications of these processes are of particular relevance. Nitrate accumulation and the release of nitrous oxide into the atmosphere due to the excessive use of fertilisers in agriculture are examples of two environmental problems in which denitrification plays a central role. © The Royal Society of Chemistry 2017.

Nitrous oxide reductase is the enzyme that catalyses the last step of the denitrification pathway, reducing nitrous oxide to dinitrogen gas. This enzyme is a functional homodimer with two copper centres, CuA and a "CuZ centre", located in different domains. The CuA centre is the electron transferring centre, while the catalytic centre is the "CuZ centre", a unique metal centre in biology - a tetranuclear copper centre with a μ4-bridging sulphide. The enzyme has been isolated with the "CuZ centre" in two different forms, CuZ(4Cu2S) and CuZ∗(4Cu1S), with the first presenting an additional μ2-sulphur atom as a bridging ligand between CuI and CuIV of the "CuZ centre", whereas the second form was identified as a water-derived molecule. Spectroscopic analysis of CuZ∗(4Cu1S), together with computational studies, indicated that there is a hydroxide bound to CuI. Genomic analysis has identified the presence of two different types of nitrous oxide reductase, the typical and "atypical", with a single member of the last group having been isolated to date, from Wolinella succinogenes. Thus, here the structure of the "typical" nitrous oxide reductase with either CuZ(4Cu2S) or CuZ∗(4Cu1S), as well as its spectroscopic and catalytic properties, will be discussed. © The Royal Society of Chemistry 2017.

Abstract Ancient structures are part of the inheritance our elders left us. These historical inheritance needs to be preserved, so the historic structures need to be rehabilitated and restored, protecting the cultural patrimony and attending to the comfort and habitability required nowadays. In order to accomplish a good and economic rehabilitation is essential to study the behaviour of traditional structures elements (masonry and wood) in order to develop adequate assessment measures and techniques. In this context it was carried out an experimental campaign to characterize the tensile mechanical behavior of the woods from the �sequeiro� wood structure, integral part of the �Quinta de Lobeira de Cima� farm. This building from the 20th century is located in Minho, Portugal. Tensile Tests were carried out for two different species of wood, chestnut and oak. The tensile tests were performed to obtain the tensile strength parallel to the fibers, using the digital image correlation (DIC) for the extension measurement.

Glass samples with a molar composition (64+x)ZnO–(16−x)B2O3–20SiO2, where x=0 or 1, were successfully synthesized using a melt-quenching technique. Based on differential thermal analysis data, the produced glass samples were submitted to controlled heat-treatments at selected temperatures (610, 615 and 620 °C) during various times ranging from 8 to 30 h. The crystallization of willemite (Zn2SiO4) within the glass matrix was confirmed by means of X-ray diffraction (XRD) and scanning electron microscopy (SEM). Under specific heat-treatment conditions, transparent nanocomposite glass-ceramics were obtained, as confirmed by UV–vis spectroscopy. The influence of temperature, holding time and glass composition on crystal growth was investigated. The mean crystallite size was determined by image analysis on SEM micrographs. The results indicated an increase on the crystallite size and density with time and temperature. The change of crystallite size with time for the heat-treatments at 615 and 620 °C depended on the glass composition. Under fixed heat-treatment conditions, the crystallite density was comparatively higher for the glass composition with higher ZnO content. © 2016 Elsevier B.V.

Weathering imposes vital effects on stony monuments. Mostly, the degree of weathering is determined by simple test results, ignoring simultaneous effects of various weathering factors. Hence, the main purpose of this study is to develop prediction models with fuzzy inference systems to determine the weathering degree of the Persepolis stone, using various accelerated ageing tests in laboratory condition and to extrapolate the results to the natural condition, considering climatic information. The results suggest reliable conformity between the prediction of the weathering degree of the stone and the weathering degree observed in the Persepolis complex in natural condition.