Metal nanoparticles and diffractive nanostructures are widely studied for enhancing light trapping efficiency in thin-film solar cells. Both have achieved high performance enhancements, but there are very few direct comparisons between the two. Also, it is difficult to accurately determine the parasitic absorption of metal nanoparticles. Here, we assess the light trapping efficiencies of both approaches in an identical absorber configuration. We use a 240 nm thick amorphous silicon slab as the absorber layer and either a quasi-random supercell diffractive nanostructure or a layer of self-assembled metal nanoparticles for light trapping. Both the plasmonic and diffractive structures strongly enhance the absorption in the red/near-infrared regime. At longer wavelengths, however, parasitic absorption becomes evident in the metal nanoparticles, which reduces the overall performance of the plasmonic approach. We have formulated a simple analytical model to assess the parasitic absorption and effective reflectivity of a plasmonic reflector and to demonstrate good agreement with the experimental data.

Nowadays there is a strong demand for intelligent packaging to provide comfort, welfare and security to owners, vendors and consumers by allowing them to know the contents and interact with the goods. This is of particular relevance for low cost, fully disposable and recyclable products, such as identification tags and medical diagnostic tests, and devices for analysis and/or quality control in food and pharmaceutical industries. However, the increase of complexity and processing capacity requires continuous power and can be addressed by the combined use of a small disposable battery, charged by a disposable solar cell, which is able to work under indoor lighting. Herein, we show a proof-of-concept of the pioneering production of thin-film amorphous silicon (a-Si:H) solar cells with an efficiency of 4{%} by plasma enhanced chemical vapour deposition (PECVD) on liquid packaging cardboard (LPC), which is commonly used in the food and beverage industries. Such accomplishment put us one step closer to this revolution by providing a flexible, renewable and extremely cheap autonomous energy packaging system. Moreover, such Si thin films take advantage of their good performance at low-light levels, which also makes them highly desirable for cheap mobile indoor applications.

{Two new Ar-BIAN Cu(II) complexes (where Ar-BIAN = bis(aryl-imino)acenaphthene) of formulations {[}CuCl2(Mes-BIAN)] (1) (Mes = 2,4,6-Me3C6H2) and {[}CuCl2(Dipp-BIAN)] (2) (Dipp = 2,6-iPr(2)C(6)H(3)) were synthesised by direct reaction of CuCl2 suspended in dichloromethane with the respective ligands Mes-BIAN (L1) and Dipp-BIAN (L2), dissolved in dichloromethane, under an argon atmosphere. Attempts to obtain these compounds by solubilising CuCl2 in methanol and adding a dichloromethane solution of the corresponding ligand, under aerobic conditions, gave also compound 1, but, in the case of L2, the Cu(I) dimer {[}CuCl(Dipp-BIAN)](2) (3) was obtained instead of compound 2. The compounds were fully characterised by elemental analyses, MALDI-TOF mass spectrometry, FT-IR, H-1 NMR and EPR spectroscopic techniques. The solid-state molecular structures of compounds 1-3 were determined by single crystal X-ray diffraction, showing the expected chelation of the Ar-BIAN ligands and two chloride ligands completing the coordination sphere of the Cu(11) centre. In the case of the complex 1, an intermediate coordination geometry around the Cu(II) centre, between square planar and tetrahedral, was revealed, while the complex 2 showed an almost square planar geometry. The structural differences and evaluation of energetic changes were rationalised by DFT calculations. Analysis of the electrochemical behaviour of complexes 1-3 was performed by cyclic voltammetry and the experimental redox potentials for Cu(II)/Cu(I) pairs have been compared with theoretical values calculated by DFT in the gas phase and in dichloromethane and methanol solutions. The complex 1 exhibited good activity in the reverse atom transfer radical polymerisation (ATRP) of styrene.}

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An integration of undoped InOx and commercial ITO thin films into laboratory assembled light shutter devices is made. Accordingly, undoped transparent conductive InOx thin films, about 100 nm thick, are deposited by radiofrequency plasma enhanced reactive thermal evaporation (rf-PERTE) of indium teardrops with no intentional heating of the glass substrates. The process of deposition occurs at very low deposition rates (0.1–0.3 nm/s) to establish an optimized reaction between the oxygen plasma and the metal vapor. These films show the following main characteristics: transparency of 87% (wavelength, λ = 632.8 nm) and sheet resistance of 52 Ω/sq; while on commercial ITO films the transparency was of 92% and sheet resistance of 83 Ω/sq. The InOx thin film surface characterized by AFM shows a uniform grain texture with a root mean square surface roughness of Rq∼2.276 nm. In contrast, commercial ITO topography is characterized by two regions: one smoother with Rq∼0.973 nm and one with big grains (Rq∼3.617 nm). For the shutters assembled using commercial ITO, the light transmission coefficient (Tr) reaches the highest value (Trmax) of 89% and the lowest (Trmin) of 1.3% [13], while for the InOx shutters these values are 80.1% and 3.2%, respectively. Regarding the electric field required to achieve 90% of the maximum transmission in the ON state (Eon), the one presented by the devices assembled with commercial ITO coated glasses is 2.41 V/μm while the one presented by the devices assembled with InOx coated glasses is smaller, 1.77 V/μm. These results corroborate the device quality that depends on the base materials and fabrication process used.

{An integration of undoped InOx and commercial ITO thin films into laboratory assembled light shutter devices is made. Accordingly, undoped transparent conductive InOx thin films, about 100 nm thick, are deposited by radiofrequency plasma enhanced reactive thermal evaporation (rf-PERTE) of indium teardrops with no intentional heating of the glass substrates. The process of deposition occurs at very low deposition rates (0.1-0.3 nm/s) to establish an optimized reaction between the oxygen plasma and the metal vapor. These films show the following main characteristics: transparency of 87% (wavelength

Os protocolos de replicação parcial de dados apresentam um grande potencial de escalabilidade. O SCORe é um protocolo para replicação parcial proposto recentemente que faz uso de controlo de concorrência multi-versão. Neste artigo abordamos um dos problemas principais que afeta o desempenho deste tipo de protocolos: a localidade dos dados, i.e., pode-se dar o caso do nó local não ter uma cópia dos dados a que pretende aceder, e nesse caso é necessário realizar uma ou mais operações de leitura remota. Assim, a não ser que se empreguem técnicas para melhorar a localidade no acesso aos dados, o número de operações de leitura remota aumenta com o tamanho do sistema, acabando por afetar o desempenho do mesmo. Nesse sentido, introduzimos um mecanismo de caching que permite replicar cópias de dados remotos de maneira a que seja poss{\'ı}vel servir localmente dados remotos enquanto que se mantém a consistência dos mesmos e a escalabilidade oferecida pelo protocolo. Avaliamos o mecanismo de caching com um benchmark conhecido da literatura e os resultados experimentais mostram resultados animadores com algum aumento no desempenho do sistema e uma redução considerável da quantidade de operações de leitura remota.

Radiation Physics and Chemistry, 98 + (2014) 132-149. doi:10.1016/j.radphyschem.2014.01.015

The wind energy production is a growing industry and the energy produced is renewable and environmentally cleaner than most of the energy production systems. The supports of the wind energy generators may be built with precast concrete elements. The precast solutions for these structures are competitive in comparison to other structural systems. The evolution of the technology for wind energy production shows a clear need for larger wind turbines and longer blades and, consequently, taller towers. The experience also shows that precast concrete solutions increase their competitiveness as the tower height increases. Offshore wind farms have some advantages in relation to onshore ones, which explains recent investments in this area. Also in this case, the durability of concrete in the sea when compared to steel, gives advantages to precast concrete in relation to other structural solutions. This paper shows the evolution of the supports of the wind energy generators and the advantages of the use of precast concrete towers.

Radiation Physics and Chemistry, 98 + (2014) 132-149. doi:10.1016/j.radphyschem.2014.01.015

In this paper we address a solution for detecting and tolerating one of the most typical concurrency bugs: atomicity violations. More specifically, we address High-Level Atomicity Violations (HLAV). High-level atomicity violations result from the misspecification of the scope of an atomic block, by splitting it in two or more atomic blocks which may be interleaved with other atomic blocks. Figure 1 shows an example of this type of atomicity violation. The intuitive idea behind HLAV is that if two shared data items (e.g., memory locations) were both accessed inside an atomic block, they are interrelated and probably the programmer intention is that there shall be no interleavings between these two accesses. Therefore, if (in the same program) this two addresses are accessed separately in different atomic blocks, an unfortunate interleaving may cause an atomicity violation.

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This paper presents a micro power light energy harvesting system for indoor environments. Light energy is collected by amorphous silicon photovoltaic (a-Si:H PV) cells, processed by a switched capacitor (SC) voltage doubler circuit with maximum power point tracking (MPPT), and finally stored in a large capacitor. The MPPT fractional open circuit voltage (V-OC) technique is implemented by an asynchronous state machine (ASM) that creates and dynamically adjusts the clock frequency of the step-up SC circuit, matching the input impedance of the SC circuit to the maximum power point condition of the PV cells. The ASM has a separate local power supply to make it robust against load variations. In order to reduce the area occupied by the SC circuit, while maintaining an acceptable efficiency value, the SC circuit uses MOSFET capacitors with a charge sharing scheme for the bottom plate parasitic capacitors. The circuit occupies an area of 0.31 mm(2) in a 130 nm CMOS technology. The system was designed in order to work under realistic indoor light intensities. Experimental results show that the proposed system, using PV cells with an area of 14 cm(2), is capable of starting-up from a 0 V condition, with an irradiance of only 0.32 W/m(2). After starting-up, the system requires an irradiance of only 0.18 W/m(2) (18 mu W/cm(2)) to remain operating. The ASM circuit can operate correctly using a local power supply voltage of 453 mV, dissipating only 0.085 mu W. These values are, to the best of the authors' knowledge, the lowest reported in the literature. The maximum efficiency of the SC converter is 70.3 % for an input power of 48 mu W, which is comparable with reported values from circuits operating at similar power levels.

This paper presents a micro power light energy harvesting system for indoor environments. Light energy is collected by amorphous silicon photovoltaic (a-Si:H PV) cells, processed by a switched capacitor (SC) voltage doubler circuit with maximum power point tracking (MPPT), and finally stored in a large capacitor. The MPPT fractional open circuit voltage (V-OC) technique is implemented by an asynchronous state machine (ASM) that creates and dynamically adjusts the clock frequency of the step-up SC circuit, matching the input impedance of the SC circuit to the maximum power point condition of the PV cells. The ASM has a separate local power supply to make it robust against load variations. In order to reduce the area occupied by the SC circuit, while maintaining an acceptable efficiency value, the SC circuit uses MOSFET capacitors with a charge sharing scheme for the bottom plate parasitic capacitors. The circuit occupies an area of 0.31 mm(2) in a 130 nm CMOS technology. The system was designed in order to work under realistic indoor light intensities. Experimental results show that the proposed system, using PV cells with an area of 14 cm(2), is capable of starting-up from a 0 V condition, with an irradiance of only 0.32 W/m(2). After starting-up, the system requires an irradiance of only 0.18 W/m(2) (18 mu W/cm(2)) to remain operating. The ASM circuit can operate correctly using a local power supply voltage of 453 mV, dissipating only 0.085 mu W. These values are, to the best of the authors' knowledge, the lowest reported in the literature. The maximum efficiency of the SC converter is 70.3 % for an input power of 48 mu W, which is comparable with reported values from circuits operating at similar power levels.

Os protocolos de replicação parcial de dados apresentam um grande potencial de escalabilidade. O SCORe é um protocolo para replicação parcial proposto recentemente que faz uso de controlo de concorrência multi-versão. Neste artigo abordamos um dos problemas principais que afeta o desempenho deste tipo de protocolos: a localidade dos dados, i.e., pode-se dar o caso do nó local não ter uma cópia dos dados a que pretende aceder, e nesse caso é necessário realizar uma ou mais operações de leitura remota. Assim, a não ser que se empreguem técnicas para melhorar a localidade no acesso aos dados, o número de operações de leitura remota aumenta com o tamanho do sistema, acabando por afetar o desempenho do mesmo. Nesse sentido, introduzimos um mecanismo de caching que permite replicar cópias de dados remotos de maneira a que seja possível servir localmente dados remotos enquanto que se mantém a consistência dos mesmos e a escalabilidade oferecida pelo protocolo. Avaliamos o mecanismo de caching com um benchmark conhecido da literatura e os resultados experimentais mostram resultados animadores com algum aumento no desempenho do sistema e uma redução considerável da quantidade de operações de leitura remota.

In 1994 fib Commission 6: Prefabrication edited a successful Planning and Design Handbook that ran to approximately 45,000 copies and was published in Spanish and German.Nearly 20 years later Bulletin 74 brings that first publication up to date. It offers a synthesis of the latest structural design knowledge about precast building structures against the background of 21st century technological innovations in materials, production and construction. With it, we hope to help architects and engineers achieve a full understanding of precast concrete building structures, the possibilities they offer and their specific design philosophy. It was principally written for non-seismic structures.

The handbook contains eleven chapters, each dealing with a specific aspect of precast building structures.
The first chapter of the handbook highlights best practice opportunities that will enable architects, design engineers and contractors to work together towards finding efficient solutions, which is something unique to precast concrete buildings.
The second chapter offers basic design recommendations that take into account the possibilities, restrictions and advantages of precast concrete, along with its detailing, manufacture, transport, erection and serviceability stages.
Chapter three describes the precast solutions for the most common types of buildings such as offices, sports stadiums, residential buildings, hotels, industrial warehouses and car parks. Different application possibilities are explored to teach us which types of precast units are commonly used in all those situations.
Chapter four covers the basic design principles and systems related to stability. Precast concrete structures should be designed according to a specific stability concept, unlike cast in-situ structures.
Chapter five discusses structural connections.
Chapters six to nine address the four most commonly used systems or subsystems of precast concrete in buildings, namely, portal and skeletal structures, wall-frame structures, floor and roof structures and architectural concrete facades.
In chapter ten the design and detailing of a number of specific construction details in precast elements are discussed, for example, supports, corbels, openings and cutouts in the units, special features related to the detailing of the reinforcement, and so forth.
Chapter eleven gives guidelines for the fire design of precast concrete structures. The handbook concludes with a list of references to good literature on precast concrete construction.

Gravity loads can affect a reinforced concrete structure’s response to seismic actions, however, traditional procedures for testing the beam behaviour do not take this effect into consideration. An experimental campaign was carried out in order to assess the influence of the gravity load on RC beam connection to the column subjected to cyclic loading. The experiments included the imposition of a conventional quasi-static test protocol based on the imposition of a reverse cyclic displacement history and of an alternative cyclic test procedure starting from the gravity load effects. The test results are presented, compared and analysed in this paper. The imposition of a cyclic test procedure that included the gravity loads effects on the RC beam ends reproduces the demands on the beams’ critical zones more realistically than the traditional procedure. The consideration of the vertical load effects in the test procedure led to an accumulation of negative (hogging) deformation. This phenomenon is sustained with the behaviour of a portal frame system under cyclic loads subject to a significant level of the vertical load, leading to the formation of unidirectional plastic hinges. In addition, the hysteretic behaviour of the RC beam ends tested was simulated numerically using the nonlinear structural analysis software – OpenSees. The beam–column model simulates the global element behaviour very well, as there is a reasonable approximation to the hysteretic loops obtained experimentally.

Sandstone building stones are important in the building elements of Portuguese monuments, particularly in the western and southern regions. Alveolization due to salt crystallization was the most important degradation pattern found in the old sandstone façades of St. Leonardo’s Church, a Portuguese monument built in Atouguia da Baleia village in the Middle Age. Its sandstone façades have a widespread distribution of deep and large alveolization patterns mainly on portals and vaults that appeared as a result of the past and present vicinity of seashore. In this paper a summary of conservation interventions carried out in the past century in St. Leonardo’s Church is presented, as well as a summary of the studies carried out in the last decade. Then the degradation patterns on the sandstone walls of St. Leonard’s Church are shown and finally the evolution of the alveolization occurred on the sandstone walls over the last sixty to seventy years is analysed. Visual inspection of sandstone walls is compared with a survey performed by laser scanning, which seems to be a powerful technology to carry out 3D geometric modelling of the building elements of stone monuments and also the 3D mapping of stone degradation patterns.

Sandstones are very important in the building elements of world’s historical and cultural heritage. The façades of St. Leonard’s church in Atouguia da Baleia village in western region of Portugal are an outstanding example of the effect of alveolization on going for several centuries. In Middle ages there was an harbour and a sodium chloride rich environment near this church was responsible for this significant stone degradation pattern.
A new approach of consolidating products application on stone walls façades based on Karsten pipe using total head to allow full absorption of stone was followed.
Experimental research, based on physical and mechanical tests, was carried out on selected representative samples of a variety of sandstones on monuments treated with ethyl silicates in order to assess the effectiveness and harmfulness of these treatments.
The comparison of results between traditional immersion applications and Karsten pipe’s based procedure on stone monument indicate the potential viability of this new approach when difficult conditions of consolidating products’ absorption occurs on stone monuments.

Experimental research was carried out about into ethyl silicate applications on sandstone samples. Consolidation was assessed by drilling strength, impregnation depth and also monotonic and cyclic uniaxial compressive tests in order to evaluate the compressive mechanical behaviour of treated sandstone. The stress–strain compression diagrams showed a significant increase in the values of mechanical parameters after consolidation treatments. The difference in compressive strength values between monotonic and cyclic compression disappears after the consolidation treatments. An equation of consolidation effect was obtained from an analytical model by means of compressive behaviour assessed by stress–strain diagrams. These sandstone samples have values of porosity similar to the more weathered variety of sandstone found in facades of monuments in the village of Atouguia da Baleia, in the western region of Portugal. The most important degradation pattern found on sandstone building stones is alveolization caused by salt crystallization since the Middle Ages.