Paper electronics is a topic of great interest due the possibility of having low-cost, disposable and recyclable electronic devices. The final goal is to make paper itself an active part of such devices. In this work we present new approaches in the selection of tailored paper, aiming to use it simultaneously as substrate and dielectric in oxide based paper field effect transistors (FETs). From the work performed, it was observed that the gate leakage current in paper FETs can be reduced using a dense microfiber/nanofiber cellulose paper as the dielectric. Also, the stability of these devices against changes in relative humidity is improved. On other hand, if the pH of the microfiber/nanofiber cellulose pulp is modified by the addition of HCl, the saturation mobility of the devices increases up to 16 cm(2) V(-1) s(-1), with an ION/IOFF ratio close to 10(5).

{{A series of new cationic and neutral (Ar-BIAN) copper(I) complexes {[}in which Ar-BIAN = bis(aryl)acenaphthenequinonediimine] was synthesised and characterised by elemental analysis, 1D and 2D NMR spectroscopy and single-crystal Xray diffraction. The cationic complexes of the general formula {[}Cu(Ar-BIAN)L-2]BF4 {[}L-2 = (PPh3)(2) (1), dppe (2), dppf (3), (AsPh3)(2) (4); Ar = 4-iPrC(6)H(4) (a), 4-MeOC6H4 (b), 4-NO2C6H4 (c), 2-iPrC(6)H(4) (d), Ph2PCH2CH2PPh2 (dppe), (Ph2PC5H4)(2)Fe (dppf)] were synthesised by reaction of {[}Cu(EPh3)(4)]BF4 (E = P or As) and equimolar amounts of Ar-BIAN ligands, or by reaction of equimolar amounts of {[}Cu(NCMe)(4)]BF4, 4-iPrC(6)H(4)-BIAN (a) and diphosphanes dppe or dppf, in dichloromethane, whereas the neutral complexes of the types {[}CuX(Ar-BIAN)(EPh3)] {[}X = Cl

{{Abstract A variety of N-heterocyclic carbene (NHC) zinc adducts of the type NHC-ZnMe2 {[}2a

A programação concorrente obriga o programador a sincronizar os acessos concorrentes a regiões de memória partilhada, contudo esta abordagem não é suficiente para evitar todas as anomalias que podem ocorrer num cenário concorrente. Executar uma sequência de operações atómicas pode causar violações de atomicidade se existir uma correlação entre essas operações, devendo o programador garantir que toda a sequência de operações é executada atomicamente. Este problema é especialmente comum quando se usam operações de pacotes ou módulos de terceiros, pois o programador pode identificar incorretamente o âmbito das regiões de código que precisam de ser atómicas para garantir o correto comportamento do programa. Para evitar este problema o programador do módulo pode criar um contrato que especifica quais as sequências de operações do módulo que devem ser sempre executadas de forma atómica. Este trabalho apresenta uma análise estática para verificação destes contratos.

The development of web applications that manipulate geo-referenced information is often supported by Application Programming Interfaces (APIs), allowing a fast development cycle for high quality applications. APIs can be used by programmers with different expertise levels and choosing an adequate API may
have a dramatic impact on the productivity achieved by those programmers. Our goal is to compare maps APIs with respect to their usability. We compare three different APIs: the Google Maps JavaScript API, the ArcGIS API for JavaScript, and the OpenLayers JavaScript Mapping Library. Our comparison is supported by
a set of software metrics and is performed in two orthogonal ways: the comparison of three implementations of the same system prototype, each using one of the APIs under scrutiny; the comparison of the APIs specifications. The main results of the study are related to the size of the APIs, with the Google API being significantly smaller than the others.

This work refers to experimental and 3D nonlinear FEA on punching. Numerical results were compared with experimental ones in order to benchmark the FE model and afterwards a parametric study was conducted, changing the reinforcement ratio, slab thickness, concrete strength and column dimensions, running a total of 360 models, where their effect on punching capacity is shown. EC2 and MC2010 provisions agreed approximately with experimental and FEA results. Based in the FEA results it is proposed an equation to predict the punching capacity with the introduction of fracture mechanics parameter, which was compared with several experimental results, giving good approximation.

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