Glass-ceramics produced from incinerated municipal solid waste

Citation:
Davim, E. a, M. H. V. a Fernandes, and R. C. C. b Monteiro. "Glass-ceramics produced from incinerated municipal solid waste." Glass Technology: European Journal of Glass Science and Technology Part A. 48 (2007): 164-167.

Abstract:

A homogeneous black coloured glass was obtained by melting the bottom ashes produced by a municipal solid waste incinerator at 1300°C for 2 h without any chemical additives. Based on thermal analysis data glass-ceramics were produced by heat treating the glass, doped with additional TiO2 as a nucleating agent, at temperatures between 870 and 1000°C. The crystalline phases precipitated during the heat treatments were identified by powder XRD and the microstructures were examined using SEM. After a heat treatment at 900°C for 2 h, the glass was converted into a fine grained glass-ceramic with uniform microstructure. The major crystalline phases precipitated in the glass-ceramics were augite (Ca(Mg,Fe)Si2O6), gehlenite (Ca2Al2SiO7) and clinopyroxene (Ca(Ti,Mg,Al)(Si,Al)2O6). Preliminary evaluation of the mechanical and chemical properties of the bottom ash glasses and glass-ceramics suggest that they have potential to compete with existing natural and commercial outdoor cladding materials.

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