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2014
Phillips, Faísca A. M. "Editorial: Organocatalysis." Mini-Rev. Org. Chem.. 11.2 (2014): 117.
Rybarczyk, Y., Coelho, T., Cardoso, T., and De Oliveira R. "Effect of avatars and viewpoints on performance in virtual world: efficiency vs. telepresence." EAI Endorsed Transactions on Creative Technologies. 14.1 (2014): e4.Website
Rybarczyk, Y., T. Coelho, T. Cardoso, and R. De Oliveira. "Effect of avatars and viewpoints on performance in virtual world: efficiency vs. telepresence." EAI Endorsed Transactions on Creative Technologies. 14.1 (2014): e4. Abstract

An increasing number of our interactions are mediated through e-technologies. In order to enhance the human’s feeling of presence into these virtual environments, also known as telepresence, the individual is usually embodied into an avatar. The natural adaptation capabilities, underlain by the plasticity of the body schema, of the human being make a body ownership of the avatar possible, in which the user feels more like his/her virtual alter ego than himself/herself. However, this phenomenon only occurs under specific conditions. Two experiments are designed to study the human’s feeling and performance according to a scale of natural relationship between the participant and the avatar. In both experiments, the human-avatar interaction is carried out by a Natural User Interface (NUI) and the individual’s performance is assessed through a behavioural index, based on the concept of affordances, and a questionnaire of presence The first experiment shows that the feeling of telepresence and ownership seem to be greater when the avatar’s kinematics and proportions are close to those of the user. However, the efficiency to complete the task is higher for a more mechanical and stereotypical avatar. The second experiment shows that the manipulation of the viewpoint induces a similar difference across the sessions. Results are discussed in terms of the neurobehavioral processes underlying performance in virtual worlds, which seem to be based on ownership when the virtual artefact ensures a preservation of sensorimotor contingencies, and simple geometrical mapping when the conditions become more artificial.

Ramos, Pinho A., Válter J. G. Lúcio, and Duarte M. V. Faria. "The effect of the vertical component of prestress forces on the punching strength of flat slabs." Engineering Structures. 76 (2014): 90-98. Abstract

The use of prestress in flat slabs is a common solution, mainly because it allows larger spans and thinner slabs. Nevertheless, smaller thicknesses near the slab-column connections, along with the superposition of high shear and flexural stresses, arise the question of the slab capacity to resist punching. The punching failure results from the superposition of shear and flexural stresses near the column, and is associated to the formation of a pyramidal plug of concrete which punches through the slab. It is a local and brittle failure. The use of prestress can increase the punching capacity of flat slabs-column connections.This work presents the experimental analysis of flat slab specimens with tendons under punching. Nine slabs were tested using unbonded prestress with high strength steel tendons. The influences on the punching capacity of the vertical component of the prestress forces resulting from inclined tendons near the column and their distance to the column are analysed. The in-plane compression force due to prestress was not applied to the slabs, in order to evaluate only the deviation force influence. This work aims to improve the understanding of the behaviour of prestressed flat slabs under punching load in order to properly evaluate the punching resistance of this kind of structures. The experimental punching loads are compared with the provisions of EC2, ACI 318-11 and MC2010. © 2014 Elsevier Ltd.

Soares, PI, AM Alves, LC Pereira, JT Coutinho, IM Ferreira, CM Novo, and J. P. Borges. "Effects of surfactants on the magnetic properties of iron oxide colloids." J Colloid Interface Sci.. 419 (2014): 46-51. AbstractWebsite

Iron oxide nanoparticles are having been extensively investigated for several biomedical applications such as hyperthermia and magnetic resonance imaging. However, one of the biggest problems of these nanoparticles is their aggregation.

Taking this into account, in this study the influence of three different surfactants (oleic acid, sodium citrate and Triton X-100) each one with various concentrations in the colloidal solutions stability was analyzed by using a rapid and facile method, the variation in the optical absorbance along time.

The synthesized nanoparticles through chemical precipitation showed an average size of 9 nm and a narrow size distribution. X-ray diffraction pattern and Fourier Transform Infrared analysis confirmed the presence of pure magnetite. SQUID measurements showed superparamagnetic properties with a blocking temperature around 155 K. In addition it was observed that neither sodium citrate nor Triton X-100 influences the magnetic properties of the nanoparticles. On the other hand, oleic acid in a concentration of 64 mM decreases the saturation magnetization from 67 to 45 emu/g. Oleic acid exhibits a good performance as stabilizer of the iron oxide nanoparticles in an aqueous solution for 24 h, for concentrations that lead to the formation of the double layer.

Barros, Teresa M., Krasimira T. Petrova, Paula Correia da Silva, and Ana Paula Esteves. "Efficient Microwave-Assisted Synthesis of 1’,2,3,3’,4,4’,6-Hepta-O-Benzyl-Sucrose and 1’,2,3,3’,4,4’-Hexa-O-Benzylsucrose." Carbohydrate Chemistry: Proven Synthetic Methods, Volume 2, Chapter 14. Eds. Gijsbert van der Marel, and Jeroen Codee. CRC Press, Taylor & Francis Group, 2014. 103-123.
Russo, J., O. Mateus, M. Marzola, and A. Balbino. "Eggs and eggshells of crocodylomorpha from the Late Jurassic of Portugal." Journal of Vertebrate Paleontology. Program and Abstracts, 2014 (2014): 218.russo_et_al_2014eggs_crocodylomorpha_portugal.pdf
Campos-Rebelo, Rogério, Anikó Costa, and Luís Gomes. "Elementary Events for Modeling of Human-System Interactions with Petri Net Models." Technological Innovation for Collective Awareness Systems - 5th {IFIP} {WG} 5.5/SOCOLNET Doctoral Conference on Computing, Electrical and Industrial Systems, DoCEIS 2014, Costa de Caparica, Portugal, April 7-9, 2014. Proceedings. 2014. 219-226. Abstract

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Marinheiro, J., O. Mateus, A. Alaoui, F. Amani, M. Nami, and C. Ribeiro. "Elephas and other vertebrate fossils near Taghrout, Morocco." Journal of Vertebrate Paleontology. Program and Abstracts, 2014 (2014): 178.marinheiro_et_al._2014_elephas_and_other_vertebrate_fossils_near_taghrout.pdf
Cunha, Jácome, João Paulo Fernandes, Jorge Mendes, Rui Pereira, and João Saraiva. "Embedding Model-Driven Spreadsheet Queries in Spreadsheet Systems." Proceedings of the 2014 IEEE Symposium on Visual Languages and Human-Centric Computing. VLHCC '14. Washington, DC, USA: IEEE Computer Society, 2014. 151-154. Abstractvlhcc14.pdf

Spreadsheets are widely used not only to define mathematical expressions, but also to store large and complex data. To query such data is usually a difficult task to perform, usually for end user. In this work we embed the textual query language in the model-driven spreadsheet environment as a spreadsheet itself. The result is an expressive and powerful query environment that has knowledge of the business logic defined by the spreadsheet data (the spreadsheet model) to guide end users constructing correct queries.

Cunha, Jácome, João P. Fernandes, Jorge Mendes, and João Saraiva. "Embedding, Evolution, and Validation of Spreadsheet Models in Spreadsheet Systems." IEEE Transactions on Software Engineering. 41.3 (2014): 241-263. Abstracttse14.pdfWebsite

This paper proposes and validates a model-driven software engineering technique for spreadsheets. The technique that we envision builds on the embedding of spreadsheet models under a widely used spreadsheet system. This means that we enable the creation and evolution of spreadsheet models under a spreadsheet system. More precisely, we embed ClassSheets, a visual language with a syntax similar to the one offered by common spreadsheets, that was created with the aim of specifying spreadsheets. Our embedding allows models and their conforming instances to be developed under the same environment. In practice, this convenient environment enhances evolution steps at the model level while the corresponding instance is automatically co-evolved. Finally, we have designed and conducted an empirical study with human users in order to assess our technique in production environments. The results of this study are promising and suggest that productivity gains are realizable under our model-driven spreadsheet development setting.

Cunha, Jácome, João P. Fernandes, Jorge Mendes, and João Saraiva Embedding, Evolution, and Validation of Spreadsheet Models in Spreadsheet Systems. HASLab - High-Assurance Software Laboratory & Universidade do Minho, 2014. Abstracttr_embedding.pdf

This paper proposes and validates a model-driven software engineering technique for spreadsheets. The technique that we envision builds on the embedding of spreadsheet models under a widely used spreadsheet system, so that models and their conforming instances are developed under the same environment. In practice, this convenient environment enhances evolution steps at the model level while the corresponding instance is automatically co-evolved. Finally, we have designed and conducted an empirical study with human users in order to assess our technique in production environments. The results of this study are promising and suggest that productivity gains are realizable under our model-driven spreadsheet development setting.

Palma, L., R. T. Rato, and AG Batista Empirical Models for Horizontal Saccadic Eye Movements. Conference on Human System Interaction. 10.1109/HSI.2014.6860450, 2014.
Silva, Micael, Angelo Miguel Figueiredo, and Eurico J. Cabrita. "Epitope mapping of imidazolium cations in ionic liquid–protein interactions unveils the balance between hydrophobicity and electrostatics towards protein destabilisation." Phys. Chem. Chem. Phys. . in press (2014). Abstract

We investigated imidazolium-based ionic liquid (IL) interactions with human serum albumin (HSA) to discern the level of cation interactions towards protein stability. STD-NMR spectroscopy was used to observe the imidazolium IL protons involved in direct binding and to identify the interactions responsible for changes in Tm as accessed by differential scanning calorimetry (DSC). Cations influence protein stability less than anions but still significantly. It was found that longer alkyl side chains of imidazolium- based ILs (more hydrophobic) are associated with a higher destabilisation effect on HSA than short-alkyl groups (less hydrophobic). The reason for such destabilisation lies on the increased surface contact area of the cation with the protein, particularly on the hydrophobic contacts promoted by the terminus of the alkyl chain. The relevance of the hydrophobic contacts is clearly demonstrated by the introduction of a polar moiety in the alkyl chain: a methoxy or alcohol group. Such structural modification reduces the degree of hydrophobic contacts with HSA explaining the lesser extent of protein destabilisation when compared to longer alkyl side chain groups: above [C2mim]+. Competition STD-NMR experiments using [C2mim]+, [C4mim]+ and [C2OHmim]+ also validate the importance of the hydrophobic interactions. The combined effect of cation and anion interactions was explored using 35Cl NMR. Such experiments show that the nature of the cation has no influence on the anion–protein contacts, still the nature of the anion modulates the cation–protein interaction. Herein we propose that more destabilising anions are likely to be a result of a partial contribution from the cation as a direct consequence of the different levels of interaction (cation–anion pair and cation–protein).

Cunha, Jácome, João Paulo Fernandes, Jorge Mendes, Rui Pereira, and João Saraiva. "ES-SQL: Visually Querying Spreadsheets." Proceedings of the 2014 IEEE Symposium on Visual Languages and Human-Centric Computing. VLHCC '14. Washington, DC, USA: IEEE Computer Society, 2014. 203-204. Abstractvlhcc14-td.pdf

This paper presents ES-SQL, an embedded tool for visually constructing queries over spreadsheets. This tool provides an expressive query environment which has knowledge on the business logic of spreadsheets, and by this knowledge it assists the user in defining the intended queries.

e Elaine Albuquerque, Guilherme Melo, António Ramos Válter Lúcio. "Estudo Teórico-Experimental da Resistência ao Punçoamento de Lajes Fungiformes de Betão Aramado com Pilar de Canto Reentrante sem Armadura de Punçoamento." 5ªs Jornadas Portuguesas de Engenharia de Estruturas, Encontro Nacional de Betão Estrutural 2014, 9º Congresso Nacional de Sismologia e Engenharia Sísmica. Lisbon: GPBE, 2014. Abstract

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Larrinaga, Pello, Carlos Chastre, Hugo C. Biscaia, and José T. San-José. "Experimental and Numerical Modelling of Basalt Textile Reinforced Mortar Behavior Under Uniaxial Tensile Stress." Materials & Design. 55.March (2014): 66-74. AbstractWebsite

During the last years several projects and studies have improved the knowledge about Textile Reinforced Mortar (TRM) technology. TRM has already been used in strengthening masonry and reinforced concrete structural elements such as walls, arches, columns and beams. This material is presented as a real alternative to the use of fibre-reinforced polymers (FRP) in situations where these composites have presented some drawbacks or their use is banned. Textile Reinforced Mortar show a complex mechanical behaviour derived from the heterogeneity of the constituent materials. This paper aims to deepen the knowledge of this composite material in terms of tensile behaviour. Following this scope, this paper presents an experimental campaign focused on thirty one TRM specimens reinforced with four different reinforcing ratios. The results are analysed and contrasted with two distinct models. i) the Aveston-Cooper-Kelly theory (ACK) which is based on a tri-linear analytical approach; and ii) a nonlinear numerical simulation with a 3D Finite Element code. The Finite Element Analysis (FEA) of the TRM tensile tests also showed no significant dependence on the basalt-to-mortar interface, i.e., the choice of a bond-slip curve in order to reproduce the bond stresses and slippages along the interface is irrelevant and it can be simply considered as rigid interface.

Cismaşiu, C., A. Narciso, and F. Amarante dos Santos. "Experimental Dynamic Characterization and Finite Element Updating of a Footbridge Structure." Journal of Performance of Constructed Facilities.10.1061/(ASCE)CF.1943-5509.0000615 (2014).Website
Cismaşiu, C., A. Narciso, and F. Amarante dos Santos. "Experimental Dynamic Characterization and Finite Element Updating of a Footbridge Structure." Journal of Performance of Constructed Facilities. 10.1061/(ASCE)CF.1943-5509.0000615 (2014). AbstractWebsite

Nowadays, modern analysis of Civil Engineering structures implies the use of increasingly sophisticated computer models, designed not only to predict the response of actual structures to different loadings, but also to simulate the effects of eventual modifications in their structural configuration. Nevertheless, it is often discovered that, when the numerical simulations are compared with experimental data, the degree of correlation is weak preventing the use of the FE models with confidence in further analyses. In such cases, FE updating techniques are available to correct the FE models, based on dynamic response records of the real structures. These updating processes usually consist of four phases: a preliminary FE modeling, an experimental modal identification, a manual sensitivity analysis and, finally, an updating of the FE model. The present paper presents all four phases of a successful updating process for the FE model of a footbridge structure. It is shown how the last phase of the process can be performed fully automatically, by coupling an optimization routine with a commercial FE analysis program.

Abreu, Rui, Jácome Cunha, João Paulo Fernandes, Pedro Martins, Alexandre Perez, and João Saraiva. "FaultySheet Detective: When Smells Meet Fault Localization." Proceedings of the 30th IEEE International Conference on Software Maintenance and Evolution. ICSME '14. Washington, DC, USA: IEEE Computer Society, 2014. 625-628. Abstracticsme14-td.pdf

This paper presents a tool, dubbed FaultySheet Detective, for aiding in spreadsheet fault localization, which combines the detection of bad smells with a generic spectrum-based fault localization algorithm.

Mateus, Octávio, Richard J. Butler, Stephen L. Brusatte, Jessica H. Whiteside, and Sébastien J. Steyer. "The first phytosaur (Diapsida, Archosauriformes) from the Late Triassic of the Iberian Peninsula." Journal of Vertebrate Paleontology. 34.4 (2014): 970-975.mateus_et_al_2014_first_phytosaur_algarve_portugal_jvp.pdfWebsite
Mallison, H., D. Schwarz-Wings, H. Tsai, C. Holliday, and O. Mateus. "Fossil longbone cartilage preserved in stegosaurs?" Journal of Vertebrate Paleontology. Program and Abstracts, 2014 (2014): 176.mallison_et_al._2014_fossil_longbone_cartilage_preserved_in_stegosaurs.pdf
Ferrás, L., M. Rebelo, and M. L. Morgado. "Fractional modelling of Pennes' bioheat equation using distributed order differential equations." 14th International Conference on Computational and Mathematical Methods in Science and Engineering (CMMSE 2014). 2014.