This paper focuses on the engineering procedures governing the synthesis of tungsten oxide nanocrystals and the formulation of printable dispersions for electrochromic applications. By that means, we aim to stress the relevancy of a proper design strategy that results in improved physicochemical properties of nanoparticle loaded inks. In the present study inkjet printable nanostructured tungsten oxide particles were successfully synthesized via hydrothermal processes using pure or acidified aqueous sol-gel precursors. Based on the proposed scheme, the structure and morphology of the nanoparticles were tailored to ensure the desired printability and electrochromic performance. The developed nanomaterials with specified structures effectively improved the electrochemical response of printed films, resulting in 2.5 times higher optical modulation and 2 times faster coloration time when compared with pure amorphous films.

Nuclear Inst. and Methods in Physics Research, B, 365 (2015) 457-461. doi:10.1016/j.nimb.2015.07.006

Journal of Physics B: Atomic, Molecular and Optical Physics, 48(2015) 185202. doi:10.1088/0953-4075/48/18/185202

Physica Scripta, 90(2015) 054009. doi:10.1088/0031-8949/90/5/054009

The study and assessment of Power Quality issues is nowadays a very important subject, particularly regarding Cyber-physical and Industrial Agents based systems, which are extremely sensitive to Power Quality disturbances. Giving students or engineers practical experience in this field requires a large investment from teaching institutions. This paper presents a laboratory device that emulates Power Quality disturbances in order to provide the required experimental expertize in the subject. It addresses limiting aspects such as harmonic distortion, flicker, sags, swells and transients. The developed system presents a good opportunity for technicians, even without deep knowledge on the field of power quality, to learn basic principles and be able to identify Power Quality events. Since the system is based on real data, represents a valuable approach giving trainees practical knowledge on the field.

Adult large-bodied theropods are often found with numerous pathologies. A large, almost complete, probably adult \\textitAllosaurus specimen from the Howe Stephens Quarry, Morrison Formation (Late Kimmeridgian–Early Tithonian), Wyoming, exhibits multiple pathologies. Pathologic bones include the left dentary, two cervical vertebrae, one cervical and several dorsal ribs, the left scapula, the left humerus, the right ischium, and two left pedal phalanges. These pathologies can be classified as follows: the fifth cervical vertebra, the scapula, several ribs and the ischium are probably traumatic, and a callus on the shaft of the left pedal phalanx II-2 is probably traumatic-infectious. Traumatically fractured elements exposed to frequent movement (e.g., the scapula and the ribs) show a tendency to develop pseudarthroses instead of a callus. The pathologies in the lower jaw and a reduced extensor tubercle of the left pedal phalanx II-2 are most likely traumatic or developmental in origin. The pathologies on the fourth cervical are most likely developmental in origin or idiopathic, that on the left humerus could be traumatic, developmental, infectious or idiopathic, whereas the left pedal phalanx IV-1 is classified as idiopathic. With exception of the ischium, all as traumatic/traumatic-infectious classified pathologic elements show unambiguous evidences of healing, indicating that the respective pathologies did not cause the death of this individual. Alignment of the scapula and rib pathologies from the left side suggests that all may have been caused by a single traumatic event. The ischial fracture may have been fatal. The occurrence of multiple lesions interpreted as traumatic pathologies again underlines that large-bodied theropods experienced frequent injuries during life, indicating an active predatory lifestyle, and their survival perhaps supports a gregarious behavior for \\textitAllosaurus. Alternatively, the frequent survival of traumatic events could be also related to the presence of non-endothermic metabolic rates that allow survival based on sporadic food consumption or scavenging behavior. Signs of pathologies consistent with infections are scarce and locally restricted, indicating a successful prevention of the spread of pathogens, as it is the case in extant reptiles (including birds).

Diplodocidae are among the best known sauropod dinosaurs. Several species were described in the late 1800s or early 1900s from the Morrison Formation of North America. Since then, numerous additional specimens were recovered in the USA, Tanzania, Portugal, and Argentina, as well as possibly Spain, England, Georgia, Zimbabwe, and Asia. To date, the clade includes about 12 to 15 nominal species, some of them with questionable taxonomic status (e.g., ‘\textit{Diplodocus}’ \textit{hayi} or \textit{Dyslocosaurus polyonychius}), and ranging in age from Late Jurassic to Early Cretaceous. However, intrageneric relationships of the iconic, multi-species genera \textit{Apatosaurus} and \textit{Diplodocus} are still poorly known. The way to resolve this issue is a specimen-based phylogenetic analysis, which has been previously implemented for \textit{Apatosaurus}, but is here performed for the first time for the entire clade of Diplodocidae.The analysis includes 81 operational taxonomic units, 49 of which belong to Diplodocidae. The set of OTUs includes all name-bearing type specimens previously proposed to belong to Diplodocidae, alongside a set of relatively complete referred specimens, which increase the amount of anatomically overlapping material. Non-diplodocid outgroups were selected to test the affinities of potential diplodocid specimens that have subsequently been suggested to belong outside the clade. The specimens were scored for 477 morphological characters, representing one of the most extensive phylogenetic analyses of sauropod dinosaurs. Character states were figured and tables given in the case of numerical characters.The resulting cladogram recovers the classical arrangement of diplodocid relationships. Two numerical approaches were used to increase reproducibility in our taxonomic delimitation of species and genera. This resulted in the proposal that some species previously included in well-known genera like \textit{Apatosaurus} and \textit{Diplodocus} are generically distinct. Of particular note is that the famous genus \textit{Brontosaurus} is considered valid by our quantitative approach. Furthermore, “\textit{Diplodocus}” hayi represents a unique genus, which will herein be called \textit{Galeamopus} gen. nov. On the other hand, these numerical approaches imply synonymization of “\textit{Dinheirosaurus}” from the Late Jurassic of Portugal with the Morrison Formation genus \textit{Supersaurus}. Our use of a specimen-, rather than species-based approach increases knowledge of intraspecific and intrageneric variation in diplodocids, and the study demonstrates how specimen-based phylogenetic analysis is a valuable tool in sauropod taxonomy, and potentially in paleontology and taxonomy as a whole.

Nowadays fiber reinforced polymer (FRP) composites play an important role in the strengthening of structures. Different methods can be used to apply these materials: the externally bonded reinforcement (EBR), and the near surface mounted (NSM) using strips and NSM rods. There are only a few studies comparing these methods or presenting an efficient model to simulate these strengthening techniques. This study looks mainly at the analysis of the interface between FRP-to-parent material bonded joints. The paper examines, through a new discrete model based on axial and shear springs, the performance of FRP-to-parent material bonded joints for EBR or NSM techniques using strips or composite rods. In order to implement the model a routine in MATLAB was developed and several bond–slip curves were assumed. The results revealed that load–slip curves or bond stresses, strains or slippages along the bonded length obtained from several bond–slip curves are similar to the analytical and other numerical solutions found in literature. In what concerns the adhesion between two different materials, and assuming the same bond characteristics for the three fiber strengthening techniques, the NSM system using FRP strips had the highest maximum load transmitted to the FRP strip combined with the lowest effective bond length. The results obtained from the proposed model were also very accurate with that obtained from an analytical solution found in literature that simulates the debonding phenomenon of FRP-to-concrete interfaces between to adjacent cracks.

A demanda de energia, faz com que o homem esteja sempre a procura de novas soluções para a sua produção. Uma opção é a energia eólica, por se tratar de uma energia limpa, renovável e inesgotável. Para se evitar a ocupação das terras férteis, é natural a busca de soluções no mar. Portanto, neste trabalho é estudado o comportamento estrutural dinâmico de uma torre treliçada em concreto armado pós-tensionado por tirantes externos idealizada para uso offshore com a finalidade de suporte para turbinas eólicas de eixo horizontal. A torre está sujeita às ações gravitacionais, aerodinâmicas e hidrodinâmicas. Para considerar estas ações desenvolveu-se um código computacional específico usando a linguagem MATLAB. É proposto um modelo simplificado para análise bi-dimensional, utilizando-se elementos de pórtico plano com a finalidade de contornar as dificuldades de uma análise tridimensional. Embora específico para este tipo de torre, o codigo permite variar geometrias, carregamentos e alterações do nível do mar. Nas cargas aerodinâmicas élevado em conta o espectro de Von Karman. As cargas hidrodinâmicas são avaliadas pela equação de Morison. As cargas nodais equivalentes são determinadas por integração ao longo do elemento estrutural de acordo com o proposto por Souza. Os tirantes pós-tensionados são monitorados para não sofrerem esforços de compressão. A análise é realizada no domínio do tempo utilizando-se o algoritmo de integração de Newmark.. Através dos procedimentos adotados foi possível obter resultados para as freqüências, deslocamentose esforços, que se mostraram coerentes com os obtidos por modelos tri dimensionais mais complexos. O código desenvolvido permitiu a análise de forma simples, eficiente e confiável de torres treliçadas de concreto armado.

Este trabalho apresenta o desenvolvimento de um software para análise de torres treliçadas em concreto armado, pós-tensionada por tirantes externos, com a finalidade de suporte para turbinas eólicas de eixo horizontal, em ambiente offshore. A torre está sujeita às ações gravitacionais, aerodinâmicas, hidrodinâmicas. Desenvolveu-se um código computacional, em linguagem MATLAB, específico para este tipo de torre. As dificuldades de uma análise tridimensional mais complexa foram reduzidas propondo-se um modelo simplificado bi-dimensional utilizando-se elementos de pórtico plano. As cargas de vento são variadas segundo o espectro de von Karman. Para as ondas marítimas e correntes são implementados o espectro de Pierson-Moskowitz e o de JONSWAP. As cargas hidrodinâmicas são avaliadas pela equação de Morison. Estas cargas são integradas ao longo dos elementos estruturais e transformadas em cargas nodais equivalentes, de acordo com o proposto por Souza. A análise é realizada no domínio do tempo com algoritmo de Newmark. Este software, por ser específico para este tipo de torre, possui facilidades na introdução de dados e na modelagem da estrutura. Com estas estratégias o modelo apresentou bons resultados para a avaliação de cargas, cálculo de freqüências naturais, resposta de deslocamentos, esforços e reações.

The Pareto distribution is a well known and important model in Statistics. It has been used to study large incomes, city population size, size of losses, stock price fluctuations, number of citations received by papers and other similar phenomena. In this work we compare the finite sample performance of several estimation methods, namely the Moment, Maximum Likelihood and Quantile Regression methods. The comparison will be made through a Monte-Carlo simulation study.The Pareto distribution is a well known and important model in Statistics. It has been used to study large incomes, city population size, size of losses, stock price fluctuations, number of citations received by papers and other similar phenomena. In this work we compare the finite sample performance of several estimation methods, namely the Moment, Maximum Likelihood and Quantile Regression methods. The comparison will be made through a Monte-Carlo simulation study.