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When (Xt)t≥0 is an ergodic process, the density function of Xt converges to some invariant density as t →∞. We will compute and study some asymptotic properties of pseudo moments estimators obtained from this invariant density, for a specific class of ergodic processes. In this class of processes we can find the Cox-Ingersoll & Ross or Dixit & Pindyck processes, among others. A comparative study of the proposed estimators with the usual estimators obtained from discrete approximations of the likelihood function will be carried out.

https://docentes.fct.unl.pt/lblm/files/redoxbiol-2018-19-274.pdf

Abstract The authors have recently proposed an innovative connector system that consists on a Glass Fibre Reinforced Polymer (GFRP) perforated plate that is embedded into Steel Fibre Reinforced Self-Compacting Concrete (SFRSCC) layers. The connection is strongly based in the mechanical interlock assured by the dowels originated from the \{SFRSCC\} passing through the holes opened on the \{GFRP\} plates. In this study, an analytical framework to evaluate the load capacity of the connections when loaded transversally was developed based on experimental pull-out tests presented in the companion paper (Part I). For a better understanding of the mechanical behaviour of the connections and to allow to make estimations of the load capacity of connection when it is conditioned by the rupture of the connector itself, pull-out pin-bearing tests with single-hole plates were executed to assess the effect of the type of \{GFRP\} on the strain distribution in the vicinity of the holes until the failure, as well as the estimated failure modes and load capacities of the connections.

The Orange Protein (ORP) is a small bacterial protein, of unknown function, that harbors a unique molybdenum/copper (Mo/Cu) heterometallic cluster, [S2MoVIS2CuIS2MoVIS2]3-, noncovalently bound. The apo-ORP is able to promote the formation and stabilization of this cluster, using CuII- and MoVIS42- salts as starting metallic reagents, to yield a Mo/Cu-ORP that is virtually identical to the native ORP. In this work, we explored the ORP capability of promoting protein-assisted synthesis to prepare novel protein derivatives harboring molybdenum heterometallic clusters containing iron, cobalt, nickel, or cadmium in place of the "central" copper (Mo/Fe-ORP, Mo/Co-ORP, Mo/Ni-ORP, or Mo/Cd-ORP). For that, the previously described protein-assisted synthesis protocol was extended to other metals and the Mo/M-ORP derivatives (M = Cu, Fe, Co, Ni, or Cd) were spectroscopically (UV-visible and electron paramagnetic resonance (EPR)) characterized. The Mo/Cu-ORP and Mo/Cd-ORP derivatives are stable under oxic conditions, while the Mo/Fe-ORP, Mo/Co-ORP, and Mo/Ni-ORP derivatives are dioxygen-sensitive and stable only under anoxic conditions. The metal and protein quantification shows the formation of 2Mo:1M:1ORP derivatives, and the visible spectra suggest that the expected {S2MoS2MS2MoS2} complexes are formed. The Mo/Cu-ORP, Mo/Co-ORP, and Mo/Cd-ORP are EPR-silent. The Mo/Fe-ORP derivative shows an EPR S = 3/2 signal (E/D approximately 0.27, g approximately 5.3, 2.5, and 1.7 for the lower M= +/-1/2 doublet, and g approximately 5.7 and 1.7 (1.3 predicted) for the upper M = +/-3/2 doublet), consistent with the presence of either one S = 5/2 FeIII antiferromagnetically coupled to two S = 1/2 MoV or one S = 3/2 FeI and two S = 0 MoVI ions, in both cases in a tetrahedral geometry. The Mo/Ni-ORP shows an EPR axial S = 1/2 signal consistent with either one S = 1/2 NiI and two S = 0 MoVI or one S = 1/2 NiIII antiferromagnetically coupled to two S = 1/2 MoV ions, in both cases in a square-planar geometry. The Mo/Cu-ORP and Mo/Cd-ORP are described as {MoVI-CuI-MoVI} and {MoVI-CdII-MoVI}, respectively, while the other derivatives are suggested to exist in at least two possible electronic structures, {MoVI-MI-MoVI} <--> {MoV-MIII-MoV}.

Fiber Reinforced Polymers (FRP) is a recent technique to strengthen timber structures and the studies available discussing the debonding between these materials are limited. Therefore, the bond assessment between FRP composites and timber substrates is a topic that needs clarification. The present work analyses the debonding process between Carbon (C) FRP laminates and timber with rupture modes consistent with Mode II interfacial fracture, i.e. with the sliding mode where the bond stresses act parallel to the plane of the bonding surface. Several single-lap shear tests were performed and the experiments showed a nonlinear local behaviour of the CFRP-to-timber interface. An interfacial bond-slip model and its calibration procedure were also presented. Furthermore, the calibrated nonlinear bond-slip model was implemented in a numerical approach where the FRP composite and the adhesive are simulated by linear and nonlinear springs and the substrate is assumed rigid. The following influences on the debonding process of the CFRP-to-timber interface were also analysed: (i) the bonding technique (Externally Bonded Reinforcement - EBR; and Near Surface Mounted - NSM); and (ii) the use of an additional device to mechanically anchor the CFRP laminate. Besides the determination of the effective bond length for each bonding technique, a new concept defining the length beyond which the force at the anchorage device does not decrease with the bonded length and a proposal to estimate its value for any bonded length was also presented and discussed. The experimental tests have shown that the NSM technique has a better performance compared to the EBR technique, independently of the installation of mechanical anchorage devices. In the case of the EBR technique, the strains in the CFRP laminate increased at its vicinities due to the clamping force applied to the anchors, which affected the final strength of the interface.

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The development of meaningful learning becomes possible when students are actively involved in solving real problems. Thus, this study intends to investigate how students of the 11th grade of a vocational course solve problems of Linear Programming, using the graphing calculator. The conclusions reached indicate that: the interpretation of the conditions of the problems is the most delicate point; the graphical approach using technology is dominant; and the difficulties raised by the problem as well as the need to discuss the results achieved are the basis for the interactions both among the students and between them and the teacher.

http://docentes.fct.unl.pt/lblm/files/inorgchem-2017-56-2210.pdf