A degradação da ligação entre compósitos de matriz polimérica reforçada por fibras (FRP) e o betão é uma das principais causas de possível rotura das vigas e lajes de betão armado reforçadas
externamente por compósitos de FRP. Desde há mais de 10 anos que se estuda, por isso, na UNL o
comportamento dessa ligação, integrado em programa mais alargado de estudo da durabilidade deste tipo de reforço, especialmente quando sujeito a condições ambientais severas que se simulam por processos artificialmente acelerados no laboratório. Em particular a degradação da aderência e o possível descolamento precoce do reforço têm sido modelados física e computacionalmente com principal incidência no uso de fibras de vidro (GFRP) e resina epoxídica. Nesta comunicação mostram-se resultados obtidos em termos de capacidade de carga, força transmitida ao reforço e tensões de aderência após envelhecimentos de pequenas vigas de betão armado (BA) por ciclos de nevoeiro salino, ciclos seco/molhado em solução salina, ciclos de temperatura entre +7,5ºC e +47,5ºC e gelo-degelo de -10ºC a +30ºC. Faz-se recomendação quanto à extensão máxima para diferentes envelhecimentos. Apresenta-se comparação entre resultados de modelação numérica e experimental.

The Radio Frequency Identification (RFID) technology is a wireless technology that uses transmitted radio signals to tag, recognize, track and trace the movement of an item automatically. The study of this technology is actually considered a hot topic in all scientific areas and has been described as a major enabling technology for the automation of many processes. Although it is not a new technology it has only recently come to the awareness of the public and widely used in many sectors and particularly in the Healthcare. This paper aims to illustrate the deployment of RFID technology in Healthcare, more precisely in infant security systems. A case study about the experience of three hospitals and one RFID technology provider is presented to highlight the main architectural characteristics, functionality, and advantages associated to its deployment. After the case studies analysis it is possible to state that the infant security systems, using the RFID technology, are not so different among research case studies: they involve RFID tagging patients, they are easy to use not requiring an extensive training and also they are installed with an interface with others security systems.

Externally bonded reinforced systems have been widely used in civil engineering. However, the problems associated with bond between structural elements are not yet fully solved. As a consequence, many researchers have been proposing tests and techniques to standardize procedures and reach better agreement for design purposes. In the present paper, an experimental program is described that was developed to characterize the glass FRP/concrete interface by double shear tests made on 15 cm side cubes with GFRP bonded on two opposite faces. The GFRP wrap had two layers applied by the wet lay-up technique and three classes of concrete were considered. With the support of the experimental program, cohesion and friction angle for GFRP–concrete interfaces were found leading to different envelope failure laws, based on the Mohr–Coulomb failure criterion for each concrete class, capable of predicting GFRP debonding. Results are discussed.

The aim was to investigate the effect of simulated low-temperature degradation (s-LTD) and hydrothermal fatigue on the degradation of three ZrO2-based dental materials. Lava, IPS, and NanoZr discs were randomly assigned to (1) Control-Storage in distilled water at 37°C; (2) Aging at 134°C for 5 h (s-LTD); (3) Thermocycling in saliva for 30,000 cycles (TF). XRD revealed that ZrO 2 m phase was identified in all groups but TF increased the m phase only for Lava. Under the FESEM, Lava showed no alterations under s-LTD, but displayed corrosion areas up to 60 μm wide after TF. We conclude that TF accelerated the degradation of Lava through an increase in the m phase and grain pull-out from the material surface.

A gene encoding Bfr (bacterioferritin) was identified and isolated from the genome of Desulfovibrio vulgaris cells, and overexpressed in Escherichia coli. In vitro, H2O2 oxidizes Fe2+ ions at much higher reaction rates than O-2. The H2O2 oxidation of two Fe2+ ions was proven by Mossbauer spectroscopy of rapid freeze-quenched samples. On the basis of the Mossbauer parameters of the intermediate species we propose that D. vulgaris Bfr follows a mineralization mechanism similar to the one reported for vertebrate H-type ferritins subunits, in which a diferrous centre at the ferroxidase site is oxidized to diferric intermediate species, that are subsequently translocated into the inner nanocavity. D. vulgaris recombinant Bfr oxidizes and stores up to 600 iron atoms per protein. This Bfr is able to bind DNA and protect it against hydroxyl radical and DNase deleterious effects. The use of H2O2 as an oxidant, combined with the DNA binding and protection activities, seems to indicate a DPS (DNA-binding protein from starved cells)-like role for D. vulgaris Bfr.

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The deactivation reaction of the [CoCp(1,4-sigma-C(4)-[Ph](4))PPh(3)] catalyst for the cyclotrimerization of acetylenes has been kinetico-mechanistically studied under different temperature, pressure, and solvent conditions. The results indicate a dramatic change in mechanism from conventional to ionic liquid solvents due to the polarity of the medium.