Purpose – The purpose of this paper is to explore the deployment of RFID technology in fashion supply chain management (FSCM). It highlights the contribution of RFID to FSCM, supporting faster logistics activities, with greater products quality, cheaper and with more responsiveness, improving customer satisfaction. Design/methodology/approach – An inductive theory building approach is used to develop a conceptual model for RFID deployment in the {FSCM} context. Secondary data analysis from a sample of six companies supports the identification and discussion of the real advantages, disadvantages and barriers felt by companies in a fashion supply chain when {RFID} technology is introduced. Findings – The logistics activities in the fashion supply chain where {RFID} technology is most widely deployed are: shipping operations, tracking of raw materials, semi-finished components and finished garments, collecting finished goods, handling processes, tracking containers, tracking products from factory to store, receiving operations, monitoring, and sorting of merchandise. In most cases, the tagging operation is performed at some stage in the production process and tag reading occurs at distribution centres or at stores. The main barrier identified to the deployment of {RFID} is the problem of interoperability. The costs associated with the technology are the main disadvantage pointed out by the companies. Practical implications – A conceptual framework is proposed exploring the {RFID} advantages and disadvantages across the fashion supply chain, the main barriers to its introduction and the fashion supply chain logistics activities in which {RFID} could be found. This represents an important contribution to companies in this industry to become more aware of {RFID.} Also, new companies which are thinking of introducing this technology could overcome its barriers easily, improving its advantages and minimizing its disadvantages. Originality/value – This paper explores the deployment of {RFID} in the fashion supply chain from the perspective of technology users.

Superoxide reductases are involved in relevant biological electron transfer reactions related to protection against oxidative stress caused by reactive oxygen species. The electrochemical features of metalloproteins belonging to the three different classes of enzymes were studied by potentio-dynamic techniques (cyclic and square wave voltammetry): desulfoferrodoxin from Desulfovibrio vulgaris Hildenborough, class I superoxide reductases and neelaredoxin from Desulfovibrio gigas and Treponema pallidum, namely class II and III superoxide reductases, respectively. In addition, a small protein, designated desulforedoxin from D. gigas, which has high homology with the N-terminal domain of class I superoxide reductases, was also investigated. A comparison of the redox potentials and redox behavior of all the proteins is presented, and the results show that SOR center II is thermodynamically more stable than similar centers in different proteins, which may be related to an intramolecular electron transfer function.

Recent issues of global heating and energy shortages are imposing a need to change our paradigm around transportation. Somehow, electric vehicles are progressively standing as a strong and necessary alternative for the society. Technically and technologically the acceptance of the EV is easier now than ever but the psychology of the consumers and the running business of internal combustion vehicles, the whole existing infrastructure are too much conservative to be changed easily. The changes in technology require changes in the engineering society and its human resources. The objective of this paper is to give a contribution to the discussion and reflection of potential future scenarios where EV/HEV‘s are spread across the society. It gives an overview of the range of knowledge and competences necessary for a sustainable and streamlined development of those. In fact, it is expected that a new kind of professional profiles need to be created or developed to supply the work market with the right human resources. The paper provides some discussion on the creation of new profiles or adaption of existing ones. Among different possible scenarios the creation of post-graduation courses for students holding undergraduate profiles in the fields referred to earlier would be an interesting and viable solution for fast response. The post graduation would be focused in specific key areas of the EV/HEV. Several factors are pointed out to endorse this scenario

The present work is devoted to the study of the decontamination of chars obtained in the co-pyrolysis of plastics, biomass and tyre wastes. The chars were extracted with several organic solvents of different polarities either individually or in sequence. The ability of each selected extractant to remove toxic pollutants was evaluated by comparing the extraction yields and by characterizing the crude extracts with a combination of chemical analysis and toxicity bioassays. Also, the mineral composition of the treated and non-treated chars was assessed. The results obtained in this study indicate that hexane is the more efficient extraction solvent to be used in the organic decontamination of chars obtained in the co-pyrolysis of plastics, tyres and biomass. A sequential extraction with solvents of increasing polarity can provide a better decontamination of the raw pyrolysis char than any individual extraction. The compounds removed from the char during the decontamination process are mainly aliphatic hydrocarbons and aromatic hydrocarbons, therefore a material that may be upgraded to be used as a fuel and/or as raw material for the organic chemical industry.

The co-combustion of coal and meat and bone meal (MBM) is a possible energetic valorization route for this residue. Nevertheless, the properties of ashes produced need to be studied. To evaluate these properties, three combustion tests were performed in a fluidized bed reactor: 1) coal combustion; 2) coal + MBM (85% + 15%) co-combustion; 3) MBM combustion. The characterization of ashes was focused on the following aspects: (1) Determination of bulk content of Cr, Zn, Ni, Cu, Pb, Cd, Hg, As, Ba, Mo, Sb, Se, Ca, Na, Mg, Fe, Al and K; (2) Leaching properties of ashes based on the European Standard EN12457-2. The eluates were characterized for some of the metals referred above and for Cr VI, CN−, pH, Cl−, F−, SO42−, dissolved organic carbon and total dissolved solids. The eluates were also characterized for ecotoxicological levels by using the following bio-indicators: bacterium V. fischeri, microalgae S. capricornutum and microcrustacean D. magna. The ashes produced in the combustion of coal and co-combustion of coal + MBM have not shown evidences of ecotoxicity, while the ashes produced in the combustion of MBM were classified as ecotoxic. An assessment of the relationship between the chemical and the ecotoxicological properties of the ashes was performed. pH seemed to be the chemical parameter that most influences the ecotoxicological level of ashes.

Differently shaped polymeric matrices were efficiently coated with stimuli-responsive hydrogels for a wide range of applications using a new methodology. By combining plasma surface activation and polymerization in supercritical media at mild conditions, we report the direct smart coating of microcarriers and membranes in gram-scale quantities with a scalable, green, and low-cost approach.

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Although rich in Cretaceous vertebrate fossils, prior to 2005 the amniote fossil record of Angola was poorly known. Two horizons and localities have yielded the majority of the vertebrate fossils collected thus far; the Turonian Itombe Formation of Iembe in Bengo Province and the Maastrichtian Mocuio Formation of Bentiaba in Namibe Province. Amniotes of the Mesozoic of Angola are currently restricted to the Cretaceous and include eucryptodire turtles, plesiosaurs, mosasaurs, pterosaurs, and dinosaurs. Recent collecting efforts have greatly expanded our knowledge of the amniote fauna of Angola and most of the taxa reported here were unknown prior to 2005.