© 2018 The Authors The use of disposable recyclable, eco-friendly, sustainable and low-cost devices with multiple functions is becoming a demand in the emerging area of the Internet of Things as a way to decrease the degree of complexity of the electronic circuits required to serve a plethora of applications. Moreover, for low-cost disposable applications, it is relevant the systems to be recyclable. The idea beyond the present study concerns to exploit our imagination with simple questions such as: What happens if it is possible to have a simple and universal device architecture, easy to implement on paper substrates, but capable to provide different multiple functionalities? It would be possible to have a common template for electronic systems on paper that would be then easily customized depending on the final application? The present study answers to these demands by reporting the physics and electronics behavior of a multigate paper transistor where paper is simultaneously the substrate and the dielectric, while a metal-oxide-semiconductor (IGZO) is used as the active channel. Moreover, the same device is able to present logic functionalities simply by varying the amplitude and frequency of the input gate signals. These transistors operate at drain voltages of 1 V with low power, exhibiting ION/IOFF{\textgreater} 104and a mobility ≈2 cm2V−1s−1, serving the specifications for a broad range of smart disposable low power electronics. To sustain all this, an analytical compact model was developed able to precisely reproduce the response of paper-based dual-gate FETs and provide full understanding of their unique and innovative operational characteristics.

Nuclear Inst. and Methods in Physics Research, B, 408 (2017) 100-102. doi:10.1016/j.nimb.2017.04.015

The functional and biological significance of the selected CASP12 targets are described by the authors of the structures. The crystallographers discuss the most interesting structural features of the target proteins and assess whether these features were correctly reproduced in the predictions submitted to the CASP12 experiment. This article is protected by copyright. All rights reserved.

Deconstruction of cellulose, the most abundant plant cell wall polysaccharide, requires the cooperative activity of a large repertoire of microbial enzymes. Modular cellulases contain non-catalytic type A Carbohydrate-Binding Modules (CBMs) that specifically bind to the crystalline regions of cellulose, thus promoting enzyme efficacy through proximity and targeting effects. Although type A CBMs play a critical role in cellulose recycling, their mechanism of action remains poorly understood. Here we produced a library of recombinant CBMs representative of the known diversity of type A modules. The binding properties of 40 CBMs, in fusion with an N-terminal green fluorescence protein (GFP) domain, revealed that type A CBMs possess the ability to recognize different crystalline forms of cellulose and chitin over a wide range of temperatures, pHs and ionic strengths. A Spirochaeta thermophila CBM64, in particular, displayed plasticity in its capacity to bind both crystalline and soluble carbohydrates under a wide range of extreme conditions. The structure of S. thermophila StCBM64C revealed an untwisted, flat, carbohydrate-binding interface comprising the side chains of four tryptophan residues in a coplanar linear arrangement. Significantly, two highly conserved asparagine side chains, each one located between two tryptophan residues, are critical to insoluble and soluble glucan recognition but not to bind xyloglucan. Thus, CBM64 compact structure and its extended and versatile ligand interacting platform illustrates how type A CBMs target their appended plant cell wall degrading enzymes to a diversity of recalcitrant carbohydrates under a wide range of environmental conditions.

This paper focuses on the analysis of InGaZnO thin-film transistors (TFTs) and circuits under the influence of different temperatures and bias stress, shedding light into their robustness when used in real-world applications. For temperature-dependent measurements, a temperature range of 15 to 85 • C was considered. In case of bias stress, both gate and drain bias were applied for 60 min. Though isolated transistors show a variation of drain current as high as 56% and 172% during bias voltage and temperature stress, the employed circuits were able to counteract it. Inverters and two-TFT current mirrors following simple circuit topologies showed a gain variation below 8%, while the improved robustness of a cascode current mirror design is proven by showing a gain variation less than 5%. The demonstration that the proper selection of TFT materials and circuit topologies results in robust operation of oxide electronics under different stress conditions and over a reasonable range of temperatures proves that the technology is suitable for applications such as smart food packaging and wearables.

Compressive stresses created by lateral external pressure on laminates are an important factor on success of the use of mechanical anchorage of externally bonded reinforcement (EBR). A program of double shear tests with imposed normal stresses on GFRP plates bonded to a concrete surface and a bond-slip model are described. Results generated numerically are summarized and used as reference values against those obtained after accelerated aging by freeze-thaw cycles, and temperature cycles of the same amplitude but range closer to the glass vitreous temperature. Numerical modelling showed that the bonded length is fully stressed prior to failure. Increasing lateral pressure led to a larger maximum bond stress and strength at the interface. Cohesion, fracture energy and internal friction angle changes are calculated and used to analyze the effects of the aforementioned cycles on the expected behaviour of the GFRP-concrete joints, namely at the interface.

A utilização de Polímeros Reforçados com Fibras (FRP) no reforço de estruturas de Betão Armado (BA) tem tido cada vez mais aceitação devido à sua elevada resistência e rigidez, baixo peso específico e excelente resistência aos efeitos dos agentes ambientais. No entanto, actualmente, é comum utilizarem-se técnicas de reforço que dificilmente permitem tirar partido da resistência total destes materiais. Com o objectivo de explorar a capacidade total de Polímeros Reforçados com Fibras de Carbono (CFRP), foram estudadas e desenvolvidas duas novas técnicas de reforço de vigas à flexão designadas por Continuous Reinforcement Embedded at Ends (CREatE) e Horizontal Near Surface Mounted Reinforcement (HNSMR). Posteriormente realizou-se um estudo comparativo entre o desempenho destes sistemas de reforço e o de duas outras técnicas já estudadas e usuais, nomeadamente os sistemas Externally Bonded Reinforcement (EBR) e Near Surface Mounted Reinforcement (NSMR). A técnica CREatE provou ser a mais eficaz de todas as alternativas testadas mobilizando a totalidade do compósito de CFRP e dotando as vigas de BA com uma maior capacidade resistente e com uma ductilidade mais elevada.Como complemento deste trabalho experimental, desenvolveu-se também um programa de cálculo em MATLAB, capaz de simular o problema em estudo através de um modelo numérico de análise não linear através do equilíbrio de secções. A representatividade dos dados obtidos foi verificada através de uma análise comparativa entre os valores numéricos e os obtidos experimentalmente.The use of Fiber Reinforced Polymers (FRP) in order to strengthen Reinforced Concrete (RC) structures has been increasingly accepted due to their strength and stiffness, low weight and excellent resistance to the effects of environmental aggressive agents. However, the bonding techniques available and described in the literature can not allow the full use of the mechanical properties of these materials and premature failures are often observed and described by several researchers. In order to explore the full capacity of CFRP composites, two new bonding strengthening techniques of RC beams when subjected to 4-point bending tests were studied and developed. For these new techniques, the designation of Continuous Reinforcement Embedded at Ends (CREatE) and Horizontal Near Surface Mounted Reinforcement (HNSMR) has been assigned. Posteriorly, a comparative study has been carried out between those strengthening systems performance and two traditional techniques, namely, the Externally Bonded Reinforcement (EBR) and Near Surface Mounted Reinforcement (NSMR). The CREatE technique has proved to be the most effective of all alternatives tested, with the full utilization of the CFRP composite and the highest strength, combined with the highest ductility. A code using MATLAB software was developed as a complement of this experimental work, which is able to simulate the problem under study through a nonlinear numerical model based on the equilibrium of sections. The representativeness of the numerical data has been verified afterwards through a comparative analysis between those and the experimental results.

In this paper, we study the performance of a portable energy dispersive X‐ray fluorescence spectrometer by making use of different filter configurations at the X‐ray tube output. To fulfill this purpose,...

Despite the success of exploiting the properties of amorphous oxide semiconductors for device applications, the charge transport in these materials is still not clearly understood. The observation of a definite Hall voltage suggests that electron transport in the conduction band is free-electron-like. However, the temperature dependence of the Hall and field-effect mobilities cannot be explained using a simple bandlike model. Here, we perform gated Hall effect measurements in field-effect transistors, which allow us to make two independent estimates of the charge carrier concentration and determine the Hall factor providing information on the energy dependence of the relaxation time. We demonstrate that the Hall factor in a range of sputtered and solution-processed quaternary amorphous oxides, such as a-InGaZnO, is close to two, while in ternary oxides, such as InZnO, it is near unity. This suggests that quaternary elements like Ga act as strong ionized impurity scattering centers in these materials.

Chemical solution deposition is a low cost, scalable and high performance technique to obtain metal oxide thin films. Recently, solution combustion synthesis has been introduced as a chemical route to reduce the processing temperature. This synthesis method takes advantage of the chemistry of the precursors as a source of energy for localized heating. According to the combustion chemistry some organic solvents can have a dual role in the reaction, acting both as solvent and fuel. In this work, we studied the role of 2-methoxyethanol in solution based synthesis of ZTO thin films and its influence on the performance of ZTO TFTs. The thermal behaviour of ZTO precursor solutions confirmed that 2-methoxyethanol acts simultaneously as a solvent and fuel, replacing the fuel function of urea. The electrical characterization of the solution based ZTO TFTs showed a slightly better performance and lower variability under positive gate bias stress when urea was not used as fuel, confirming that the excess fuel contributes negatively to the device operation and stability. Solution based ZTO TFTs demonstrated a low hysteresis ($Δ$V = −0.3 V) and a saturation mobility of 4–5 cm2 V−1 s−1.

This paper investigates whether the model uncertainty of reinforced recycled aggregate concrete (RAC) beams subjected to bending differs from that of reinforced natural aggregate concrete (NAC) beams. An introductory remark concerning the importance of the codification of RAC structural design is made and notions concerning model uncertainties and their role on structural codification are given. Afterwards, the criteria used in the construction of a database of RAC and NAC beams are referred before presenting the key findings of an analysis on the model uncertainty of the cracking, yielding and ultimate moments of beams subjected to four-point bending tests. The analytical moments were calculated following Eurocode 2 provisions. Probabilistic models for model uncertainties are proposed. Negligible differences in the model uncertainty of NAC and RAC beams are reported.

Cellulosomes are sophisticated multi-enzymatic nanomachines produced by anaerobes to effectively deconstruct plant structural carbohydrates. Cellulosome assembly involves the binding of enzyme-borne dockerins (Doc) to repeated cohesin (Coh) modules located in a non-catalytic scaffoldin. Docs appended to cellulosomal enzymes generally present two similar Coh-binding interfaces supporting a dual-binding mode, which may confer increased positional adjustment of the different complex components. Ruminococcus flavefaciens’ cellulosome is assembled from a repertoire of 223 Doc-containing proteins classified into 6 groups. Recent studies revealed that Docs of groups 3 and 6 are recruited to the cellulosome via a single-binding mode mechanism with an adaptor scaffoldin. To investigate the extent to which the single-binding mode contributes to the assembly of R. flavefaciens cellulosome, the structures of two group 1 Docs bound to Cohs of primary (ScaA) and adaptor (ScaB) scaffoldins were solved. The data revealed that group 1 Docs display a conserved mechanism of Coh recognition involving a single-binding mode. Therefore, in contrast to all cellulosomes described to date, the assembly of R. flavefaciens cellulosome involves single but not dual-binding mode Docs. Thus, this work reveals a novel mechanism of cellulosome assembly and challenges the ubiquitous implication of the dual-binding mode in the acquisition of cellulosome flexibility.

The Spheroolithidae oospecies Guegoolithus turolensis, putatively attributed to non-hadrosauroid styracosterns was first described in the Barremian of the Iberian Basin, and later reported in the Valanginian–Hauterivian of the Cameros Basin, with both occurrences separated by a few hundred kilometres but by over 10 million years.