Publications

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2018
Rebocho, S., C. M. Cordas, R. Viveiros, and T. Casimiro. "Development of a ferrocenyl-based MIP in supercritical carbon dioxide: Towards an electrochemical sensor for bisphenol A." Journal of Supercritical Fluids. 135 (2018): 98-104. AbstractWebsite
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2009
Cordas, C. M., N. M. T. Lourenco, P. Vidinha, CAM Afonso, S. Barreiros, L. P. Fonseca, and J. M. S. Cabral. "New conducting biomaterial based on Ion Jelly (R) technology for development of a new generation of biosensors." New Biotechnology. 25 (2009): S138-S139. AbstractWebsite
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2003
Cordas, C. M., A. S. Viana, S. Leupold, F. P. Montforts, and L. M. Abrantes. "Self-assembled monolayer of an iron(III) porphyrin disulphide derivative on gold." Electrochemistry Communications. 5.1 (2003): 36-41. AbstractWebsite

A novel iron(III) porphyrin disulphide derivative have been successfully immobilised on gold surfaces by self-assembly. The redox response of the modified electrodes was compared with the obtained for a similar iron porphyrin in solution, confirming the immobilisation of the metalloporphyrin. The gravimetric data obtained by electrochemical quartz crystal microbalance (EQCM) during adsorption allowed an estimation of the electrode coverage, providing further evidence for the formation of the porphyrin SAM. The modified electrodes were also measured by conventional and imaging ellipsometry. The electrocatalytic activity of the two modified electrodes was tested for the reduction of the molecular oxygen. (C) 2002 Elsevier Science B.V. All rights reserved.

2002
Abrantes, L. M., C. M. Cordas, and E. Vieil. "EQCM study of polypyrrole modified electrodes doped with Keggin-type heteropolyanion for cation detection." Electrochimica Acta. 47.9 (2002): 1481-1487. AbstractWebsite

The incorporation of a Keggin-type heteropolyanion, the phosphotungstate ([PW12O40](3-)), into polypyrrole has been achieved during the electrochemical preparation of the polymer films in aqueous solution. The redox behaviour of these modified electrodes is described by using cyclic voltammetry (CV) and electrochemical quartz crystal microbalance (EQCM). The data allowed to estimate the doping level that indicates the extent of the heteropolyanion insertion. It is found that the polymer films, in aqueous solution, exhibit sensibility to cations, namely to Na+. (C) 2002 Elsevier Science Ltd. All rights reserved.