The thermal behavior and transport properties of several ion jellys (IJs), a composite that results from the combination of gelatin with an ionic liquid (IL), were investigated by dielectric relaxation spectroscopy (DRS), differential scanning calorimetry (DSC), and pulsed field gradient nuclear magnetic resonance spectroscopy (PFG NMR). Four different ILs containing the dicyanamide anion were used: 1-butyl-3-methylimidazolium dicyanamide (BMIMDCA), 1-ethyl-3-methylimidazolium dicyanamide (EMIMDCA), 1-butyl-1-methylpyrrolidinium dicyanamide (BMPyrDCA), and 1-butylpyridinium dicyanamide (BPyDCA); the bulk ILs were also investigated for comparison. A glass transition was detected by DSC for all materials, ILs and IJs, allowing them to be classified as glass formers. Additionally, an increase in the glass transition temperature upon dehydration was observed with a greater extent for IJs, attributed to a greater hindrance imposed by the gelatin matrix after water removal, rendering the IL less mobile. While crystallization is observed for some ILs with negligible water content, it was never detected for any IJ upon thermal cycling, which persist always as fully amorphous materials. From DRS measurements, conductivity and diffusion coefficients for both cations (D+) and anions (D–) were extracted. D+ values obtained by DRS reveal excellent agreement with those obtained from PFG NMR direct measurements, obeying the same VFTH equation over a large temperature range (ΔT ≈ 150 K) within which D+ varies around 10 decades. At temperatures close to room temperature, the IJs exhibit D values comparable to the most hydrated (9%) ILs. The IJ derived from EMIMDCA possesses the highest conductivity and diffusion coefficient, respectively, 10–2 S·cm–1 and 10–10 m2·s–1. For BMPyrDCA the relaxational behavior was analyzed through the complex permittivity and modulus formalism allowing the assignment of the detected secondary relaxation to a Johari–Goldstein process. Besides the relevant information on the more fundamental nature providing physicochemical details on ILs behavior, new doorways are opened for practical applications by using IJ as a strategy to produce novel and stable electrolytes for different electrochemical devices.

The paleontological richness of Morocco has been scientifically known since at least the early 20th century. The region of the Middle Atlas, more specifically the Boulemane area, has been however only sparsely studied since the 1960s when it provided vertebrate fossils from the Middle Jurassic. In September 2013, a Moroccan-Portuguese expedition to the village of Taghrout, Boulemane, made excavations in a Pleistocene fossil site that once was a small high-altitude sedimentary basin, uncharted in previous geological maps. The excavations yielded bone material from large mammals, the most common findings are elephants ascribed to Elephas, but artiodactyls, turtles, and in-situ Acheulean tools were also collected. This represents a new and important paleontological and archeological site. In addition to the discoveries of Taghrout, the expedition also retrieved Quaternary vertebrate material from a nearby cave and found new Jurassic localities, with arcosaur bones and dinosaur footprints, in El Mers.

An emerging trend in the field of Graphics Processing Unit (GPU) computing is the harnessing of multiple devices to cope with scalability and performance requirements. How- ever, multi-GPU execution adds new challenges to the al- ready complex world of General Purpose computing on GPUs (GPGPU), such as the efficient problem decomposition, and dealing with device heterogeneity. To this extent, we pro- pose the use of the Marrow algorithmic skeleton framework (ASkF) to abstract most of the details intrinsic to the pro- gramming of such platforms. To the best of our knowledge, Marrow is the first ASkF to support skeleton nesting on single and (now) multiple GPU systems. In this paper we present how it can transparently distribute the execution of skeleton compositions among a set of, possibly, hetero- geneous devices. An experimental evaluation assesses the proposal’s effectiveness, from a scalability and performance perspective, with good results.

http://docentes.fct.unl.pt/lblm/files/inorgchem-2014-53-12799.pdf

Mosasaurs are marine squamates with a 32.5 million-year history from their appearance at 98 Ma to their extinction at the K-Pg boundary (65.5 Ma). Using a database of 43 generic and 94 species-level taxa, we compare the taxonomic diversity and patterns of morphological disparity in mosasaurs with sea level, sea surface temperature, and stable carbon isotope curves for the Upper Cretaceous to explore factors that may have influenced their evolution. No single factor unambiguously accounts for all radiations, diversification, and extinctions; however, the broader patterns of taxonomic diversification and
morphological disparity point to niche differentiation in a “fishing up” scenario under the influence of “bottom-up” selective pressures. The most likely driving force in mosasaur evolution was high productivity in the Late Cretaceous, driven by tectonically controlled sea levels and climatically controlled ocean stratification and nutrient delivery. When productivity collapsed at the end of the Cretaceous, coincident with bolide impact, mosasaurs became extinct.

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Despite being staggeringly error prone, spreadsheets are a highly flexible programming environment that is widely used in industry. In fact, spreadsheets are widely adopted for decision making, and decisions taken upon wrong (spreadsheet-based) assumptions may have serious economical impacts on businesses, among other consequences. This paper proposes a technique to automatically pinpoint potential faults in spreadsheets. It combines a catalog of spreadsheet smells that provide a first indication of a potential fault, with a generic spectrum-based fault localization strategy in order to improve (in terms of accuracy and false positive rate) on these initial results. Our technique has been implemented in a tool which helps users detecting faults. To validate the proposed technique, we consider a well-known and well-documented catalog of faulty spreadsheets. Our experiments yield two main results: we were able to distinguish between smells that can point to faulty cells from smells and those that are not capable of doing so; and we provide a technique capable of detecting a significant number of errors: two thirds of the cells labeled as faulty are in fact (documented) errors.

This technical report describes the research goals and results of the SpreadSheet as a Programming Paradigm research project. This was a project funded by Funda{\c c}ão para a Ciencia e Tecnologia – FCT: the Portuguese research foundation, under reference FCOMP-01-0124-FEDER-010048, that ran from May 2010 till July 2013. This report includes the complete document reporting the results achieved during the project execution, which was submitted to FCT for evaluation on October 2013. It describes the goals of the project, and the different research tasks presenting the deliver- ables of each of them. It also presents the management and result dissemination work performed during the project's execution. The document includes also a self assess- ment of the achieved results, and a complete list of scientific publications describing the contributions of the project. Finally, this document includes the FCT evaluation report.

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Two new Late Jurassic (uppermost Late Kimmeridgian) dinosaur eggshell sites are described, Casal da Rola and Porto das Barcas, both near Lourinha˜, central-west Portugal. Casal da Rola yields eggshells with an obliquiprismatic morphotype comparable to those from a nest with the associated fossil embryos from Paimogo, tentatively assigned to the theropod Lourinhanosaurus antunesi. The Porto das Barcas eggshells have a dendrospherulitic morphotype with a prolatocanaliculate pore system. This morphotype was also recognised in eggshells from a clutch with associated Torvosaurus embryos at the Porto das Barcas locality. A preliminary cladistic analysis of eggshell morphology suggests theropod affinities for the Casal da Rola eggs, but is unable to resolve the phylogenetic position of the Porto das Barcas eggs. The eggshells at both sites are preserved in distal flood plain mudstones and siltstones. Carbonate concretions within the deposits indicate paleosol development.

This study addresses the energetic performance of an attached-sunspace applied to an existing residential building in Portugal. Four configurations (two attached, one integrated and one partially integrated) are studied in six different climatic zones. In addition other key parameters are considered such as ventilation (with or without natural ventilation), shading devices (one external and two internal configurations), number of glazed surface layers (single glazed and double glazed) and orientation (South, East and West). The thermal performance analysis, carried out using a dynamic simulation code, proved that energy savings for retrofitting design can be very important and that in climates with warm summers the risk of overheating can be considerably diminished through an accurate analysis based on modeling.