Publications

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Journal Article
Aviles, Teresa, and Gabriela Teixeira. "Monocyclopentadienyl compounds of vanadium." Rev. Inorg. Chem.. 12 (1993): 95-155. Abstract

A review with 59 refs. describing the synthesis, structure, and reactivity of monocyclopentadienyl compds. of vanadium. [on SciFinder(R)]

Aviles, T., F. Barroso, P. Royo, and J. H. Noordik. "New Eta-Allyl Eta-Cyclopentadienylcobalt Cations." J Organomet Chem. 236 (1982): 101-108. AbstractWebsite
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Aviles, T., F. Barroso, and P. Royo. "New Neutral and Cationic Cyclopentadienylcobalt Complexes." J Organomet Chem. 326 (1987): 423-429. AbstractWebsite
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Pedras, B., E. Oliveira, H. Santos, L. Rodriguez, R. Crehuet, T. Aviles, J. L. Capelo, and C. Lodeiro. "A new tripodal poly-imine indole-containing ligand: Synthesis, complexation, spectroscopic and theoretical studies." Inorg Chim Acta. 362 (2009): 2627-2635. AbstractWebsite

A novel flexible tripodal ligand derived from 3-methylindole, ("InTREN" L), and its mononuclear Zn(II), Cu(II), Ni(II), Hg(II) and Pd(II) complexes are described. All compounds gave analytically pure solid samples. Characterisation of the compounds was accomplished by (1)H NMR, IR and absorption spectroscopies, matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF-MS) and elemental analysis and their geometry optimized using density functional theory (DFT).Time-dependent-density functional theory (TD-DFT) calculations have been used to assign the lowest energy absorption bands of the free ligand and the Zn(II) complex. The system is a very good candidate for in situ recognition/coordination effects by MALDI-TOF-MS spectrometry and absorption spectroscopy. The presence of three indole groups in InTREN opens up the possibility to synthesize new three-dimensional self-assembly supramolecular structures. (C) 2008 Elsevier B.V. All rights reserved.

Aviles, T., A. Dinis, M. G. B. Drew, and V. Felix. "A novel infinite 1-D chain of Silver(I) bridged by trans-azobenzene." Monatsh Chem. 131 (2000): 1305-1310. AbstractWebsite

The self-assembly of Ag[BF(4)] with trans-azobenzene in dichloromethane yields a new coordination polymer ([Ag(mu -trans-azobenzene)H(2)O] [BF(4)])(n) which was characterized by X-ray single crystal diffraction. The crystal consists of 1-D zigzag cationic chains made up from [Ag(H(2)O)](+) units linked by trans-azobenzene bridges and BF(4)(-) anions. Hydrogen bonding interactions between the chains and BF(4)(-) anions occur via intermolecular C-H . . .F and O-H . . .F contacts, and the crystal displays a 2-D supramolecular structure.

Aviles, T., and J. H. Teuben. "On the Reactivity of V(Eta-C6h3me3-1,3,5)2i." J Organomet Chem. 253 (1983): 39-43. AbstractWebsite
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Casimiro, T., F. Montilla, S. Garcia, T. Aviles, S. Raeissi, A. Shariati, C. J. Peters, M. N. da Ponte, and A. Aguiar-Ricardo. "Phase behaviour of the catalyst dicarbonyl (eta(5)-cyclopentadienyl)-cobalt in carbon dioxide." J Supercrit Fluid. 31 (2004): 1-8. AbstractWebsite

The phase behaviour of the binary mixture of carbon dioxide and the cobalt complex dicarbonyl(eta(5)-cyclopentadienyl)-cobalt, CPCo(CO)(2), has been investigated. This organometallic compound is one of the most effective catalysts of cyclotrimerization reactions of arylisocyanates and alkynes. Vapour-liquid equilibrium (VLE) measurements were undertaken in a static analytical apparatus at 313.15, 323.15 and 363.15 K at pressures up to 15 MPa. p, T isopleths were measured by a synthetic method in a Cailletet apparatus. Nine different compositions ranging from 17.56 to 94.23 mol% of CO2 were measured up to 15 MPa. Modelling with the Peng-Robinson equation of state (PR EOS) gave reasonable results in the correlation of the experimental phase equilibrium compositions using two temperature-dependent interaction parameters. (C) 2003 Elsevier B.V. All rights reserved.

Aviles, T., M. A. A. F. D. Carrondo, M. F. M. Piedade, and G. Teixeira. "Reaction of [Mn(Ch3-Eta-5-C5h4)(Co)2pph3] with Iodine - Crystal-Structure of Diiodobis(Triphenylphosphineoxide)Manganese(Ii)." J Organomet Chem. 388 (1990): 143-149. AbstractWebsite
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Aviles, T., and P. Royo. "Reactions of Monocyclopentadienyl-Cobalt Cations with Nucleophiles." J Organomet Chem. 221 (1981): 333-337. AbstractWebsite
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Maiti, Biplab K., Teresa Avilés, Marta S. P. Carepo, Isabel Moura, Sofia R. Pauleta, and José J. G. Moura. "Rearrangement of Mo-Cu-S Cluster Reflects the Structural Instability of Orange Protein Cofactor." Z. Anorg. Allg. Chem.. 639.8-9 (2013): 1361-1364.