Publications

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2014
Fliedel, C., D. Vila-Viçosa, M. J. Calhorda, S. Dagorne, and T. Avilés. "Dinuclear Zinc N-heterocyclic Carbene Complexes for either the Controlled Ring-opening polymerization (ROP) of lactide or the Controlled Degradation of Polylactide under Mild Conditions." Chem.Cat.Chem. . 6 (2014): 1357-1367.
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2011
Aviles, T., S. Jansat, M. Martinez, F. Montilla, and C. Rodriguez. "Deactivation of the Cobalt Catalyst for the Cyclotrimerization of Acetylenes in Ionic Liquids: Solvent Effects on the Mechanism and Thermal and Pressure Activation Parameters." Organometallics. 30 (2011): 3919-3922. AbstractWebsite

The deactivation reaction of the [CoCp(1,4-sigma-C(4)-[Ph](4))PPh(3)] catalyst for the cyclotrimerization of acetylenes has been kinetico-mechanistically studied under different temperature, pressure, and solvent conditions. The results indicate a dramatic change in mechanism from conventional to ionic liquid solvents due to the polarity of the medium.