@article {Kullberg2017239, title = {Crystal growth in zinc borosilicate glasses}, journal = {Journal of Crystal Growth}, volume = {457}, year = {2017}, note = {

cited By 0

}, pages = {239-243}, abstract = {

Glass samples with a molar composition (64+x)ZnO{\textendash}(16-x)B2O3{\textendash}20SiO2, where x=0 or 1, were successfully synthesized using a melt-quenching technique. Based on differential thermal analysis data, the produced glass samples were submitted to controlled heat-treatments at selected temperatures (610, 615 and 620 {\textdegree}C) during various times ranging from 8 to 30 h. The crystallization of willemite (Zn2SiO4) within the glass matrix was confirmed by means of X-ray diffraction (XRD) and scanning electron microscopy (SEM). Under specific heat-treatment conditions, transparent nanocomposite glass-ceramics were obtained, as confirmed by UV{\textendash}vis spectroscopy. The influence of temperature, holding time and glass composition on crystal growth was investigated. The mean crystallite size was determined by image analysis on SEM micrographs. The results indicated an increase on the crystallite size and density with time and temperature. The change of crystallite size with time for the heat-treatments at 615 and 620 {\textdegree}C depended on the glass composition. Under fixed heat-treatment conditions, the crystallite density was comparatively higher for the glass composition with higher ZnO content. {\textcopyright} 2016 Elsevier B.V.

}, doi = {10.1016/j.jcrysgro.2016.07.022}, url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-84979663984\&doi=10.1016\%2fj.jcrysgro.2016.07.022\&partnerID=40\&md5=52e08ac03a5bd06f970d730c5ae2192d}, author = {Kullberg, A.T.G. and Lopes, A.A.S. and Veiga, J.P.B. and Monteiro, R. C. C.} } @article {Kullberg201679, title = {Formation and crystallization of zinc borosilicate glasses: Influence of the ZnO/B2O3 ratio}, journal = {Journal of Non-Crystalline Solids}, volume = {441}, year = {2016}, note = {

cited By 3

}, pages = {79-85}, abstract = {

Different glasses based on the ZnO-B2O3-SiO2 system, with a ZnO content >= 60 mol\% and a fixed SiO2 content (20 mol\%), were synthesised using a melt-quenching method. Glass samples with zinc oxide concentrations as high as 65 mol\% were prepared successfully without deteriorating the glass-forming ability. The glass samples were submitted to controlled heat-treatments, and the effect of the ZnO/B2O3 molar ratio on the formation of crystalline phases within the glass matrix was investigated by means of differential thermal analysis (DTA), X-ray diffraction (XRD) and scanning electron microscopy (SEM). DTA results indicated that the glass transition and the onset crystallization temperatures of the studied glasses tended to increase with the increment on the ZnO/B2O3 ratio. XRD data showed that the zinc binary crystalline phases, willemite (Zn2SiO4), a zinc orthosilicate, and zinc borate (Zn3B2O6) could be present in the crystallized glasses, depending on the heat-treatment conditions. The formation of willemite was promoted by an increasing ZnO/B2O3 ratio. Microstructural observations performed by SEM indicated that under controlled experimental parameters (glass composition, heat-treatment temperature and time) the precipitation of nanocrystals within the glass matrix can be achieved, resulting in transparent and translucent willemite glass-ceramics. {\textcopyright} 2016 Elsevier B.V. All rights reserved.

}, doi = {10.1016/j.jnoncrysol.2016.03.022}, url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-84962668494\&doi=10.1016\%2fj.jnoncrysol.2016.03.022\&partnerID=40\&md5=572320330addbb6cdc9d64f8b0944b60}, author = {Kullberg, A.T.G. and Lopes, A.A.S. and Veiga, J.P.B. and Lima, M. M. R. A. and Monteiro, R. C. C.} }