@article {Martins2004,
	title = {{Syntheses and structures of molybdenum and tungsten pentabenzylcyclopentadienyl complexes: New chlorination reactions}},
	journal = {Journal of Organometallic Chemistry},
	volume = {689},
	year = {2004},
	note = {n/a},
	pages = {2368{\textendash}2376},
	abstract = {<p>[M(CpBz)(CO)3CH3] (M=Mo, 2a, W, 2b; CpBz=C5(CH2Ph)5) have been prepared and reacted with PCl5 and PhI {\textperiodcentered} Cl2. Depending on the metal and on the chlorinating reagent used [Mo(CpBz) ($η$2-COCH3)Cl3], 3, [W(CpBz)Cl4], 4, [Mo(CpBz)(CO)3Cl], 5 and [Mo(CpBz)Cl4], 6 have been obtained. The molecular structures of all compounds are reported and two conformations have been characterised for the benzyl substituents. In complexes 2a, 2b and 5 one phenyl ring bends towards the metals while in 3 and 4 the five phenyls point opposite to the metals. {\textcopyright} 2004 Elsevier B.V. All rights reserved.</p>
},
	keywords = {Carbonyl insertion, Chlorination, molybdenum, Oxidation, Pentabenzylcyclopentadienyl, Tungsten},
	issn = {0022328X},
	doi = {10.1016/j.jorganchem.2004.04.027},
	author = {Martins, Ana M. and Branquinho, Rita and Cui, Jinlan and Dias, Alberto R. and Duarte, M. Teresa and Fernandes, Jos{\'e} and Rodrigues, Sandra S.}
}
