<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="6.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Vitor Rosa,</style></author><author><style face="normal" font="default" size="100%">Realista, Sara</style></author><author><style face="normal" font="default" size="100%">Mourato, Ana</style></author><author><style face="normal" font="default" size="100%">Abrantes, Luisa Maria</style></author><author><style face="normal" font="default" size="100%">Henriques, Joao</style></author><author><style face="normal" font="default" size="100%">Calhorda, Maria Jose</style></author><author><style face="normal" font="default" size="100%">Aviles, Teresa</style></author><author><style face="normal" font="default" size="100%">Drew, Michael G. B.</style></author><author><style face="normal" font="default" size="100%">Felix, Vitor</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">{1,1 `-Bis(diphenylphosphino)ferrocene bridging two mono(cyclopentadienyl) cobalt moieties: Synthesis, structure, electrochemistry and DFT studies}</style></title><secondary-title><style face="normal" font="default" size="100%">{JOURNAL OF ORGANOMETALLIC CHEMISTRY}</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2012</style></year><pub-dates><date><style  face="normal" font="default" size="100%">{AUG 1}</style></date></pub-dates></dates><volume><style face="normal" font="default" size="100%">{712}</style></volume><pages><style face="normal" font="default" size="100%">{52-56}</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;{Reaction of {[}Co(eta(5)-C5H5)(CO)(2)], 1, with 1,1'-bis(diphenylphosphino)ferrocene (dppf) yields the new trinuclear complex {[}Co(eta(5)-C5H5)(CO)](2)(mu-dppf), 2, which was structurally characterised by single crystal X-ray diffraction and showed two Co(eta(5)-C5H5)(CO) moieties covalently linked by a dppf bridge. Electrochemical studies in dichloromethane revealed that both Co(I) and Fe(II) in the precursors were oxidized to Co(II)/Co(III) and Fe(III), respectively. On the other hand, in 2 the two first oxidation waves were assigned to Co, the Fe(II) centre requiring a higher potential than in free dppf. DFT calculations showed that the HOMOs of 2 were localised in the Co fragments, owing to the destabilisation of the Co(eta(5)-C5H5)(CO) orbitals after binding dppf. (C) 2012 Elsevier B.V. All rights reserved.}&lt;/p&gt;
</style></abstract><notes><style face="normal" font="default" size="100%">&lt;p&gt;n/a&lt;/p&gt;
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