<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="6.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Vitor Rosa,</style></author><author><style face="normal" font="default" size="100%">Fliedel, Christophe</style></author><author><style face="normal" font="default" size="100%">Ghisolfi, Alessio</style></author><author><style face="normal" font="default" size="100%">Pattacini, Roberto</style></author><author><style face="normal" font="default" size="100%">Aviles, Teresa</style></author><author><style face="normal" font="default" size="100%">Braunstein, Pierre</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">{Influence of a thioether function in short-bite diphosphine ligands on the nature of their silver complexes: structure of a trinuclear complex and of a coordination polymer}</style></title><secondary-title><style face="normal" font="default" size="100%">{DALTON TRANSACTIONS}</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2013</style></year></dates><number><style face="normal" font="default" size="100%">{34}</style></number><volume><style face="normal" font="default" size="100%">{42}</style></volume><pages><style face="normal" font="default" size="100%">{12109-12119}</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;{New cationic Ag(I) complexes were prepared by reaction of AgBF4 with two thioether-functionalized bis-(diphenylphosphino) amine ligands, Ph2PN(p-ArSMe)PPh2 (L1) and Ph2PN(n-PrSMe)PPh2 (L2), and compared with those obtained from the unfunctionalized ligands Ph2PN(Ph)PPh2 (L3) and Ph2PN(n-Bu)PPh2 (L4), respectively. The complex {[}Ag-3(mu(3)-Cl)(2)(mu(2)-L1-P, P)(3)](BF4) (1 center dot BF4) contains a triangular array of Ag centres supported by three bridging L1 ligands and two triply-bridging chlorides. In contrast, ligand L2 led to the coordination polymer {[}\{Ag-2(mu(3)-L2,-P,P,S)(2)(MeCN)(2)\}\{Ag-2(mu(2)-L2-P,P)(2)(MeCN)(2) \}(BF4)(4)](n) (2) in which the tethered thioether group connects intermolecularly a Ag2 unit to the diphosphine bridging the other Ag2 unit. With L3 and L4, two similar complexes were obtained, {[}Ag-2(mu(2)-L3)(BF4)(2)] (3) and {[}Ag-2(mu(2)-L4)(BF4)(2)] (4), respectively, with bridging diphosphine ligands and a BF4 anion completing the coordination sphere of the metal. Complexes 1 center dot BF4 center dot CH2Cl2, 2 center dot THF, 3 center dot 3CH(2)Cl(2) and 4 have been fully characterized, including by single crystal X-ray diffraction.}&lt;/p&gt;
</style></abstract><notes><style face="normal" font="default" size="100%">&lt;p&gt;n/a&lt;/p&gt;
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