<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="6.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Pinto, P.</style></author><author><style face="normal" font="default" size="100%">Calhorda, M. J.</style></author><author><style face="normal" font="default" size="100%">Felix, V.</style></author><author><style face="normal" font="default" size="100%">Aviles, T.</style></author><author><style face="normal" font="default" size="100%">Drew, M. G. B.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Syntheses and crystal structures of polynuclear Cu(I) complexes containing the 1,1 '-bis(diphenylphosphino)-ferrocene ligand</style></title><secondary-title><style face="normal" font="default" size="100%">Monatshefte Fur Chemie</style></secondary-title><alt-title><style face="normal" font="default" size="100%">Monatsh Chem</style></alt-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">bis(diphenylphosphino)methane</style></keyword><keyword><style  face="normal" font="default" size="100%">bridging ligands</style></keyword><keyword><style  face="normal" font="default" size="100%">copper</style></keyword><keyword><style  face="normal" font="default" size="100%">crystal structures</style></keyword><keyword><style  face="normal" font="default" size="100%">dft calculations</style></keyword><keyword><style  face="normal" font="default" size="100%">dppf</style></keyword><keyword><style  face="normal" font="default" size="100%">Electrochemistry</style></keyword><keyword><style  face="normal" font="default" size="100%">energy</style></keyword><keyword><style  face="normal" font="default" size="100%">heteropolymetallic complexes</style></keyword><keyword><style  face="normal" font="default" size="100%">molecular-structures</style></keyword><keyword><style  face="normal" font="default" size="100%">numerical-integration</style></keyword><keyword><style  face="normal" font="default" size="100%">system</style></keyword><keyword><style  face="normal" font="default" size="100%">trinuclear copper(i) acetylides</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2000</style></year><pub-dates><date><style  face="normal" font="default" size="100%">Dec</style></date></pub-dates></dates><urls><web-urls><url><style face="normal" font="default" size="100%">&lt;Go to ISI&gt;://000166378000005</style></url></web-urls></urls><number><style face="normal" font="default" size="100%">12</style></number><volume><style face="normal" font="default" size="100%">131</style></volume><pages><style face="normal" font="default" size="100%">1253-1265</style></pages><isbn><style face="normal" font="default" size="100%">0026-9247</style></isbn><language><style face="normal" font="default" size="100%">English</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;The reaction between [Cu(NCMe)(4)][PF6] and 1,1'-bis-(diphenylphosphino)-ferrocene (dppf) in several ratios, solvents, and conditions led to the synthesis and structural characterization of the Cu(I) complexes [Cu(dppf)(Odppf)] [PF6] (1), [(dppf)Cu(mu -dppf)Cu(dppf)][PF6](2) (2), and [(dppf)Cu(mu -Cl)(2)Cu(dppf)] (3). Although 1 and the cation in 2 were known, the first was structurally characterized for the first time, exhibiting a significant asymmetry in the coordination sphere of Cu(I)) owing to the presence of oxygen. In 2, the PF6- anion led to an interesting crystal packing with large open channels containing water. Finally, DFT calculations on a model of 3 showed that its HOMO exhibits, besides Fe, a significant Cu and Cl character, which is reflected in its electrochemical properties.&lt;/p&gt;
</style></abstract><accession-num><style face="normal" font="default" size="100%">ISI:000166378000005</style></accession-num><notes><style face="normal" font="default" size="100%">&lt;p&gt;391VYTimes Cited:9Cited References Count:47&lt;/p&gt;
</style></notes><auth-address><style face="normal" font="default" size="100%">Calhorda, MJITQB, Apart 127, P-2781901 Oeiras, PortugalITQB, Apart 127, P-2781901 Oeiras, PortugalITQB, P-2781901 Oeiras, PortugalUniv Lisbon, Fac Ciencias, Dept Quim &amp; Bioquim, P-1749016 Lisbon, PortugalUniv Aveiro, Dept Quim, P-3810193 Aveiro, PortugalUniv Nova Lisboa, Fac Ciencias &amp; Tecnol, Ctr Quim Fina &amp; Biotecnol, Dept Quim, P-2825114 Monte De Caparica, PortugalUniv Reading, Dept Chem, Reading RG6 6AD, Berks, England</style></auth-address></record></records></xml>