<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="6.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Casimiro, T.</style></author><author><style face="normal" font="default" size="100%">Montilla, F.</style></author><author><style face="normal" font="default" size="100%">Garcia, S.</style></author><author><style face="normal" font="default" size="100%">Aviles, T.</style></author><author><style face="normal" font="default" size="100%">Raeissi, S.</style></author><author><style face="normal" font="default" size="100%">Shariati, A.</style></author><author><style face="normal" font="default" size="100%">Peters, C. J.</style></author><author><style face="normal" font="default" size="100%">da Ponte, M. N.</style></author><author><style face="normal" font="default" size="100%">Aguiar-Ricardo, A.</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">Phase behaviour of the catalyst dicarbonyl (eta(5)-cyclopentadienyl)-cobalt in carbon dioxide</style></title><secondary-title><style face="normal" font="default" size="100%">Journal of Supercritical Fluids</style></secondary-title><alt-title><style face="normal" font="default" size="100%">J Supercrit Fluid</style></alt-title></titles><keywords><keyword><style  face="normal" font="default" size="100%">chemistry</style></keyword><keyword><style  face="normal" font="default" size="100%">CO2</style></keyword><keyword><style  face="normal" font="default" size="100%">cpco(co)(2)</style></keyword><keyword><style  face="normal" font="default" size="100%">organometallic catalyst</style></keyword><keyword><style  face="normal" font="default" size="100%">pr eos</style></keyword><keyword><style  face="normal" font="default" size="100%">pressures</style></keyword><keyword><style  face="normal" font="default" size="100%">vle</style></keyword></keywords><dates><year><style  face="normal" font="default" size="100%">2004</style></year><pub-dates><date><style  face="normal" font="default" size="100%">Sep</style></date></pub-dates></dates><urls><web-urls><url><style face="normal" font="default" size="100%">&lt;Go to ISI&gt;://000224260400001</style></url></web-urls></urls><number><style face="normal" font="default" size="100%">1</style></number><volume><style face="normal" font="default" size="100%">31</style></volume><pages><style face="normal" font="default" size="100%">1-8</style></pages><isbn><style face="normal" font="default" size="100%">0896-8446</style></isbn><language><style face="normal" font="default" size="100%">English</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;The phase behaviour of the binary mixture of carbon dioxide and the cobalt complex dicarbonyl(eta(5)-cyclopentadienyl)-cobalt, CPCo(CO)(2), has been investigated. This organometallic compound is one of the most effective catalysts of cyclotrimerization reactions of arylisocyanates and alkynes. Vapour-liquid equilibrium (VLE) measurements were undertaken in a static analytical apparatus at 313.15, 323.15 and 363.15 K at pressures up to 15 MPa. p, T isopleths were measured by a synthetic method in a Cailletet apparatus. Nine different compositions ranging from 17.56 to 94.23 mol% of CO2 were measured up to 15 MPa. Modelling with the Peng-Robinson equation of state (PR EOS) gave reasonable results in the correlation of the experimental phase equilibrium compositions using two temperature-dependent interaction parameters. (C) 2003 Elsevier B.V. All rights reserved.&lt;/p&gt;
</style></abstract><accession-num><style face="normal" font="default" size="100%">ISI:000224260400001</style></accession-num><notes><style face="normal" font="default" size="100%">&lt;p&gt;859JWTimes Cited:5Cited References Count:17&lt;/p&gt;
</style></notes><auth-address><style face="normal" font="default" size="100%">Aguiar-Ricardo, AUniv Nova Lisboa, Fac Ciencias &amp; Tecnol, Dept Quim, CWFB,REQUIMTE, P-2829516 Caparica, PortugalUniv Nova Lisboa, Fac Ciencias &amp; Tecnol, Dept Quim, CWFB,REQUIMTE, P-2829516 Caparica, PortugalUniv Nova Lisboa, Fac Ciencias &amp; Tecnol, Dept Quim, CWFB,REQUIMTE, P-2829516 Caparica, PortugalDelft Univ Technol, Fac Sci Appl, Lab Appl Thermodynam &amp; Phase Equilibria, NL-2628 BL Delft, Netherlands</style></auth-address></record></records></xml>