<?xml version="1.0" encoding="UTF-8"?><xml><records><record><source-app name="Biblio" version="6.x">Drupal-Biblio</source-app><ref-type>17</ref-type><contributors><authors><author><style face="normal" font="default" size="100%">Kauf, Thomas</style></author><author><style face="normal" font="default" size="100%">Vitor Rosa,</style></author><author><style face="normal" font="default" size="100%">Fliedel, Christophe</style></author><author><style face="normal" font="default" size="100%">Pattacini, Roberto</style></author><author><style face="normal" font="default" size="100%">Deibel, Naina</style></author><author><style face="normal" font="default" size="100%">Aviles, Teresa</style></author><author><style face="normal" font="default" size="100%">Sarkar, Biprajit</style></author><author><style face="normal" font="default" size="100%">Braunstein, Pierre</style></author></authors></contributors><titles><title><style face="normal" font="default" size="100%">{Reactivity of TCNE and TCNQ derivatives of quinonoid zwitterions with Cu(I)}</style></title><secondary-title><style face="normal" font="default" size="100%">{DALTON TRANSACTIONS}</style></secondary-title></titles><dates><year><style  face="normal" font="default" size="100%">2015</style></year></dates><number><style face="normal" font="default" size="100%">{12}</style></number><volume><style face="normal" font="default" size="100%">{44}</style></volume><pages><style face="normal" font="default" size="100%">{5441-5450}</style></pages><language><style face="normal" font="default" size="100%">eng</style></language><abstract><style face="normal" font="default" size="100%">&lt;p&gt;{The reactions of TCNE- and TCNQ-functionalized (TCNE: tetracyanoethylene and TCNQ: 7,7', 8,8'-tetra-cyanoquinodimethane) zwitterionic benzoquinonemonoimines with a Cu(I)-BIAN complex (BIAN = bis-(o, o'-bisisopropylphenyl)acenaphthenequinonediimine) have been investigated and found to follow a diversity of interesting patterns. The complexes {[}Cu(BIAN)(NCMe)(L2)]BF4 (2) and {[}Cu(BIAN)(L2)(2)]BF4 (4) were obtained by reacting {[}Cu(BIAN)(NCMe) 2] BF4 (1) with one and two equivalents of L2, respectively. Following similar procedures, the complexes {[}Cu(BIAN)(NCMe)(L3)] BF4 (6) and {[}Cu(BIAN)(L3)(2)]BF4 (7) were obtained by reaction of 1 with L3. The reaction of 2 with 0.5 equiv. of 4,4'-bipyridine afforded {[}\{Cu(BIAN)-(L2)\}(2)(mu-4,4'-bipyridine)](BF4)(2) (3). The complexes were characterized by multinuclear NMR, IR and UV-Vis spectroscopic techniques, mass spectrometry, cyclic voltammetry and elemental analysis. The molecular structures of complexes 3 center dot 4CH(2)Cl(2) and 4 center dot CH2Cl2 were determined by single crystal X-ray diffraction. An unexpected coordination polymer {[}Cu(L2(-))(2)](infinity) (5) was also structurally characterized, which contains Cu(II) centres chelated by two N, O-bound ligands resulting from the monodeprotonation of L2.}&lt;/p&gt;
</style></abstract><notes><style face="normal" font="default" size="100%">&lt;p&gt;n/a&lt;/p&gt;
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