@article {1386,
	title = {Phase behaviour of the catalyst dicarbonyl (eta(5)-cyclopentadienyl)-cobalt in carbon dioxide},
	journal = {Journal of Supercritical Fluids},
	volume = {31},
	number = {1},
	year = {2004},
	note = {<p>859JWTimes Cited:5Cited References Count:17</p>
},
	month = {Sep},
	pages = {1-8},
	abstract = {<p>The phase behaviour of the binary mixture of carbon dioxide and the cobalt complex dicarbonyl(eta(5)-cyclopentadienyl)-cobalt, CPCo(CO)(2), has been investigated. This organometallic compound is one of the most effective catalysts of cyclotrimerization reactions of arylisocyanates and alkynes. Vapour-liquid equilibrium (VLE) measurements were undertaken in a static analytical apparatus at 313.15, 323.15 and 363.15 K at pressures up to 15 MPa. p, T isopleths were measured by a synthetic method in a Cailletet apparatus. Nine different compositions ranging from 17.56 to 94.23 mol\% of CO2 were measured up to 15 MPa. Modelling with the Peng-Robinson equation of state (PR EOS) gave reasonable results in the correlation of the experimental phase equilibrium compositions using two temperature-dependent interaction parameters. (C) 2003 Elsevier B.V. All rights reserved.</p>
},
	keywords = {chemistry, CO2, cpco(co)(2), organometallic catalyst, pr eos, pressures, vle},
	isbn = {0896-8446},
	url = {<Go to ISI>://000224260400001},
	author = {Casimiro, T. and Montilla, F. and Garcia, S. and Aviles, T. and Raeissi, S. and Shariati, A. and Peters, C. J. and da Ponte, M. N. and Aguiar-Ricardo, A.}
}
