@article {1377,
	title = {Deactivation of the Cobalt Catalyst for the Cyclotrimerization of Acetylenes in Ionic Liquids: Solvent Effects on the Mechanism and Thermal and Pressure Activation Parameters},
	journal = {Organometallics},
	volume = {30},
	number = {15},
	year = {2011},
	note = {<p>799SYTimes Cited:0Cited References Count:42</p>
},
	month = {Aug 8},
	pages = {3919-3922},
	abstract = {<p>The deactivation reaction of the [CoCp(1,4-sigma-C(4)-[Ph](4))PPh(3)] catalyst for the cyclotrimerization of acetylenes has been kinetico-mechanistically studied under different temperature, pressure, and solvent conditions. The results indicate a dramatic change in mechanism from conventional to ionic liquid solvents due to the polarity of the medium.</p>
},
	keywords = {alkynes, chemistry, complexes, isomerization, Kinetics, Ligands, parallel reaction pathways, substitution-reactions, transition, water},
	isbn = {0276-7333},
	url = {<Go to ISI>://000293307600003},
	author = {Aviles, T. and Jansat, S. and Martinez, M. and Montilla, F. and Rodriguez, C.}
}
