@article { ISI:000338612900024,
	title = {{Synthesis and characterization of {[}S2MoS2Cu(n-SPhF)](2-) (n = o, m, P) clusters: Potential F-19-NMR structural probes for Orange Protein}},
	journal = {{INORGANIC CHEMISTRY COMMUNICATIONS}},
	volume = {{45}},
	year = {2014},
	note = {<p>n/a</p>
},
	month = {{JUL}},
	pages = {{97-100}},
	abstract = {<p>{Three fluorinated Mo-Cu-thiolate isomers,{[}Ph4Ph{[}S2MoS2Cu(n-SPhF)], {[}n-SPhF = 2-fluorothiophenol (la)], 3-fluorothiophenol (lb), and 4-fluorothiophenol (1c)] were synthesized and spectroscopically characterized. The F-19-NMR signal of the fluorine atom in the.benzene has different chemical shift for each isomer, which is highly influenced by the local environment that can be manipulated by different solvents and solutes. The fluorine-19 chemical shift is an advantageous NMR structural probe in alternative to H-1-NMR {[}B.K. Maiti, T. Aviles, M. Matzapetakis, I. Moura, S.R. Pauleta, JJ.G. Moura, Eur. J. Inorg. Chem. (2012) 4159.], that can be used to provide local information on the pocket of the metal cluster in the Orange Protein (ORP). (C) 2014 Elsevier B.V. All rights reserved.}</p>
},
	issn = {{1387-7003}},
	doi = {{10.1016/j.inoche.2014.04.006}},
	author = {Maiti, Biplab K. and Aviles, Teresa and Moura, Isabel and Pauleta, Sofia R and Moura, Jose J. G.}
}
